3-碘-1,2,4,5-四甲基苯合成路线 （共 19 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; copper(l) iodide; trifluoroacetic acid sodium salt T=150 - 180°C; 15 h;
参考文献
Chemistry Letters, , p. 135 - 136
反应条件
copper(l) iodide in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=150 - 180°C; 15 h;
参考文献
Chemistry Letters, , p. 135 - 136
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; copper(l) iodide; trifluoroacetic acid sodium salt T=150 - 180°C; 15 h;
参考文献
Suzuki, Hitomi; Yoshida, Yoshiki; Osuka, Atsuhiro
Chemistry Letters, 1982 , p. 135 - 136
反应条件
copper(l) iodide in N,N,N',N',N'',N''-hexamethylphosphoric triamide T=150 - 180°C; 15 h;
参考文献
Suzuki, Hitomi; Yoshida, Yoshiki; Osuka, Atsuhiro
Chemistry Letters, 1982 , p. 135 - 136
反应条件
copper in N,N-dimethyl-formamide T=150°C;
参考文献
Lukmanov,V.G. et al.
Journal of Organic Chemistry USSR (English Translation), 1974 , vol. 10, p. 2019
Zhurnal Organicheskoi Khimii, 1974 , vol. 10, p. 2000 - 2001
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; copper(l) iodide
1.) 100-110 deg C, 2.) DMSO, 100-110 deg C, 12 h; Yield given. Multistep reaction;
参考文献
Suzuki, Hitomi; Miyoshi, Keiko; Shinoda, Misao
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 6 p. 1765 - 1766
反应条件
1: 1.) CuI, HMPA, 2.) NaN3 / 1.) 100-110 deg C, 2.) 70-90 deg C, 24 h
2: LiAlH4 / tetrahydrofuran
View Scheme
参考文献
Suzuki, Hitomi; Miyoshi, Keiko; Shinoda, Misao
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 6 p. 1765 - 1766
反应条件
air; 2,3-dimethyl-naphthalene in acetonitrile
0.00277778 h; microwave irradiation;
参考文献
Enquist, Per-Anders; Nilsson, Peter; Larhed, Mats
Organic Letters, 2003 , vol. 5, # 25 p. 4875 - 4878
反应条件
1: Cu / dimethylformamide / 150 °C
2: (i) aq. HNO3, (ii) NaOH, (iii) KMnO4
View Scheme
参考文献
Lukmanov,V.G. et al.
Journal of Organic Chemistry USSR (English Translation), 1974 , vol. 10, p. 2019
Zhurnal Organicheskoi Khimii, 1974 , vol. 10, p. 2000 - 2001
