1.1: 90.2 percent / aq. acetic acid; ZnCl2; Zn / 16 h / 60 °C
2.1: BuLi / diethyl ether / 4 h
2.2: diethyl ether / -78 - 20 °C
3.1: aq. HCl / tetrahydrofuran / 3 h / Heating
View Scheme
参考文献
Jones, David J.; Gibson, Vernon C.; Green, Simon M.; Maddox, Peter J.; White, Andrew J. P.; Williams, David J.
Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 11037 - 11046
1.1: BuLi / diethyl ether
1.2: 90.5 percent / tetrahydrofuran; diethyl ether / 1 h / 20 °C
2.1: 90.2 percent / aq. acetic acid; ZnCl2; Zn / 16 h / 60 °C
3.1: BuLi / diethyl ether / 4 h
3.2: diethyl ether / -78 - 20 °C
4.1: aq. HCl / tetrahydrofuran / 3 h / Heating
View Scheme
参考文献
Jones, David J.; Gibson, Vernon C.; Green, Simon M.; Maddox, Peter J.; White, Andrew J. P.; Williams, David J.
Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 11037 - 11046
1.1: BuLi / diethyl ether / 4 h
1.2: diethyl ether / -78 - 20 °C
2.1: aq. HCl / tetrahydrofuran / 3 h / Heating
View Scheme
参考文献
Jones, David J.; Gibson, Vernon C.; Green, Simon M.; Maddox, Peter J.; White, Andrew J. P.; Williams, David J.
Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 11037 - 11046
1.1: Na / tetrahydrofuran / Heating
1.2: 239.6 g / tetrahydrofuran / 1 h
2.1: BuLi / diethyl ether
2.2: 90.5 percent / tetrahydrofuran; diethyl ether / 1 h / 20 °C
3.1: 90.2 percent / aq. acetic acid; ZnCl2; Zn / 16 h / 60 °C
4.1: BuLi / diethyl ether / 4 h
4.2: diethyl ether / -78 - 20 °C
5.1: aq. HCl / tetrahydrofuran / 3 h / Heating
View Scheme
参考文献
Jones, David J.; Gibson, Vernon C.; Green, Simon M.; Maddox, Peter J.; White, Andrew J. P.; Williams, David J.
Journal of the American Chemical Society, 2005 , vol. 127, # 31 p. 11037 - 11046
