3-O-苯甲基-1,2-o-异亚丙基-alpha-d-呋喃葡萄糖合成路线 （共 5 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
0.5 h;
参考文献
Lohman, Gregory J. S.; Seeberger, Peter H.
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7541 - 7543
反应条件
1.1: Bu2SnO
1.2: tetrabutylammonium iodide
2.1: dimethyldioxirane / CH2Cl2; acetone / 0.17 h / 0 °C
2.2: 73 percent / ZnCl2 / CH2Cl2; diethyl ether / 18 h / 20 °C
3.1: tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Lohman, Gregory J. S.; Seeberger, Peter H.
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7541 - 7543
反应条件
1.1: imidazole
2.1: Bu2SnO
2.2: tetrabutylammonium iodide
3.1: dimethyldioxirane / CH2Cl2; acetone / 0.17 h / 0 °C
3.2: 73 percent / ZnCl2 / CH2Cl2; diethyl ether / 18 h / 20 °C
4.1: tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Lohman, Gregory J. S.; Seeberger, Peter H.
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7541 - 7543
反应条件
1.1: dimethyldioxirane / CH2Cl2; acetone / 0.17 h / 0 °C
1.2: 73 percent / ZnCl2 / CH2Cl2; diethyl ether / 18 h / 20 °C
2.1: tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Lohman, Gregory J. S.; Seeberger, Peter H.
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7541 - 7543
反应条件
1.1: NaOMe / methanol
2.1: imidazole
3.1: Bu2SnO
3.2: tetrabutylammonium iodide
4.1: dimethyldioxirane / CH2Cl2; acetone / 0.17 h / 0 °C
4.2: 73 percent / ZnCl2 / CH2Cl2; diethyl ether / 18 h / 20 °C
5.1: tetrabutylammonium fluoride / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Lohman, Gregory J. S.; Seeberger, Peter H.
Journal of Organic Chemistry, 2003 , vol. 68, # 19 p. 7541 - 7543
