1: NaBr / Pd(PPh3)4 / tetrahydrofuran; methanol / 1.5 h / Ambient temperature
2: 1) BuLi / 1) THF-hexane, room temperature, 30 min, 2) room temperature, 4 h
View Scheme
参考文献
Tsukahara, Yuhko; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi
Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 10 p. 3013 - 3014
R(a)-2,2'-binaphthyl-bis-((R)-1-phenylethyl)phosphoramidite; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium in ethanol
T=20°C; 16 h; Title compound not separated from byproducts.;
参考文献
Ohmura, Toshimichi; Hartwig, John F.
Journal of the American Chemical Society, 2002 , vol. 124, # 51 p. 15164 - 15165
(S)-mesophore confined Pd(II) catalyst in tetrahydrofuran
T=40°C; Alkylation; Title compound not separated from byproducts;
参考文献
Johnson, Brian F. G.; Raynor, Stuart A.; Shephard, Douglas S.; Mashmeyer, Thomas; Thomas, John Meurig; Sankar, Gopinthar; Bromley, Stefen; Oldroyd, Richard; Gladden, Lynn; Mantle, Mike D.
Chemical Communications, 1999 , # 13 p. 1167 - 1168
(R)-mesopore confined Pd(II) catalyst in tetrahydrofuran
T=40°C; Alkylation; Product distribution; Further Variations:Catalysts;
参考文献
Johnson, Brian F. G.; Raynor, Stuart A.; Shephard, Douglas S.; Mashmeyer, Thomas; Thomas, John Meurig; Sankar, Gopinthar; Bromley, Stefen; Oldroyd, Richard; Gladden, Lynn; Mantle, Mike D.
Chemical Communications, 1999 , # 13 p. 1167 - 1168
