乙酰溴-Alpha-D-葡萄糖酮酸甲基酯合成路线 （共 53 条）
反应条件
1: mercury (II)-cyanide 2: sodium methylate; methanol 3: barium hydroxide; water View Scheme
参考文献
Helferich; Berger
Chemische Berichte, 1957 , vol. 90, p. 2492,2495
反应条件
1: 61 percent / Ag2O, isoquinoline / 1 h / 20 °C 2: 80 percent / cyclohexene / Pd/C / propan-2-ol / 0.5 h / Heating View Scheme
参考文献
Rossignol, Jean-Francois; Stachulski, Andrew V.
Journal of Chemical Research - Part S, 1999 , # 1 p. 44 - 45
反应条件
1: 80 percent / CdCO3 / toluene / 2.5 h / Heating 2: 65 percent / aq. NaOH / methanol / 24 h / Ambient temperature View Scheme
参考文献
Wu, Yinqiu; Blackwell, Leonard F.
Steroids, 1993 , vol. 58, # 10 p. 452 - 456
反应条件
1: silver carbonate; benzene 2: methanol; barium hydroxide; water View Scheme
参考文献
Wotiz et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1704,1706
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Pelzer
Hoppe-Seyler's Zeitschrift fuer Physiologische Chemie, 1959 , vol. 314, p. 234,239
反应条件
potassium carbonate in acetone 6 h; Heating;
参考文献
Yaegashi; Nokata; Sawada; Furuta; Yokokura; Miyasaka
Chemical and Pharmaceutical Bulletin, 1992 , vol. 40, # 1 p. 131 - 135
反应条件
1: 50 percent / CdCO3 / toluene / 2 h / Heating 2: KOH / methanol / Ambient temperature View Scheme
参考文献
Sasaki, Yasuhiro; Morita, Toshinobu; Kuramoto, Takashi; Mizutani, Kenji; Ikeda, Ryuko; Tanaka, Osamu
Agricultural and Biological Chemistry, 1988 , vol. 52, # 1 p. 207 - 210
反应条件
1.1: 55 percent / silver trifluoromethanesulfonate; tetramethylurea / CH2Cl2 / 12 h / -20 °C
2.1: sodium methoxide / methanol / 24 h / 20 °C
2.2: 40 percent / Ba(OH)2 / methanol / 24 h / 20 °C
View Scheme
参考文献
Kim, Hee-Joo; Ki, Chang Ahn; Seung, Jin Ma; Gee, Shirley J.; Hammock, Bruce D.
Journal of Agricultural and Food Chemistry, 2007 , vol. 55, # 10 p. 3750 - 3757
反应条件
in acetone
3 h; Heating;
参考文献
Leydet, Alain; Jeantet-Segonds, Christine; Barthelemy, Philippe; Boyer, Bernard; Roque, Jean Pierre
Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands, 1996 , vol. 115, # 10 p. 421 - 426
反应条件
1: 58 percent / 48 h / Ambient temperature
2: 84 percent / 1 M NaOH (aq.) / Ambient temperature
View Scheme
参考文献
Dalgaard, Lars
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 10 p. 923 - 928
反应条件
1: 75 percent / aq. CdCO3 / acetonitrile / 2 h / 70 °C
2: 60 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene / 1,2-dichloro-ethane / 1 h / 0 °C
View Scheme
参考文献
Lu, Xin-An; Chou, Chien-Hung; Wang, Cheng-Chung; Hung, Shang-Cheng
Synlett, 2003 , # 9 SPEC. ISS. p. 1364 - 1366
