diphenylditellane in benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 1h) in the presence of 7-10 molpercent (t-Bu)2NO (radical); reaction completely inhibited;;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
diphenylditellane in benzene Irradiation (UV/VIS); nitrogen atmosphere; mercurial and PhTeTePh (1.2 equiv) in deoxygenated solvent irradiated (250-W sunlamp, 40 °C, 1h);; filtration; solvent removed (vacuum); PhCH2TePh analysed by (1)H NMR, GLC and GCMS;;
参考文献
Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K.
Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
mercury dichloride in diethyl ether
absol. ether; 24h standing at ambient temp.; 2h heating to reflux; careful decomposition with ice and H2SO4;; pure;;
参考文献
Hilpert, S.; Gruettner, G.
Ber. Dtsch. Chem. Ges., 1915 , vol. 48, p. 906 - 915
benzylsulfene chloride in dichloromethane
byproducts: (PhCH2)2S; addn. of Hg-compound to a soln. of organic compound cooled to -20°C;
参考文献
Nikanorov, V. A.; Rozenberg, V. I.; Gavrilova, G. A.; Reutov, O. A.
Doklady Chemistry, 1982 , vol. 262, p. 4 - 7
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 262, # 1 p. 108 - 113
in benzene
dibenzylmercury dissolved in benzene, added to benzene suspn. of Pd complex under N2 over 2 h, solvent evapd., residue treated at 65°C (0.005 torr) for 3 h; washed with warm ethanol, residue treated with charcoal and recrystd. from benzene/petroleum ether, elem. anal.;
参考文献
Anderson, Gordon K.
Organometallics, 1983 , vol. 2, p. 665 - 668
