in dichloromethane-d2 under N2 or Ar; small amt. of water added to soln. of B compd. in CD2Cl2at 283 K; reversible react.; not isolated; detd. by (19)F NMR spectra;
in deuterated toluene under Ar; in NMR tube; C6F4(B(C6F5)2)2 dissolved in toluene-d8; capped; cooled to -78°C; degassed H2O (1-2 equiv.) in toluene-d8 injected; cooled to -60°C; not isolated; monitored by NMR spectra;
参考文献
Lewis, Stewart P.; Chai, Jianfang; Collins, Scott; Sciarone, Timo J. J.; Henderson, Lee D.; Fan, Cheng; Parvez, Masood; Piers, Warren E.
Organometallics, 2009 , vol. 28, # 1 p. 249 - 263
in deuterated toluene under Ar; in NMR tube; C6F4(B(C6F5)2)2 dissolved in toluene-d8; capped; cooled to -78°C; degassed H2O (more than 2 equiv.) in toluene-d8 injected; cooled to -60°C; not isolated; monitored by NMR spectra;
参考文献
Lewis, Stewart P.; Chai, Jianfang; Collins, Scott; Sciarone, Timo J. J.; Henderson, Lee D.; Fan, Cheng; Parvez, Masood; Piers, Warren E.
Organometallics, 2009 , vol. 28, # 1 p. 249 - 263
C6(2)H5C(2)H3 in deuterated toluene byproducts: C6F5H, (C6H5)2CHC6(2)H4C(2)H3; under 2 atm of H2 at 110°C for 48 h, then at 110°C; not isolated, detected by MS;
in deuterated toluene under Ar; in NMR tube; C6F4(B(C6F5)2)2 dissolved in toluene-d8; capped; cooled to -78°C; degassed H2O (large excess) in toluene-d8 injected; cooled to -60°C; not isolated; monitored by NMR spectra;
参考文献
Lewis, Stewart P.; Chai, Jianfang; Collins, Scott; Sciarone, Timo J. J.; Henderson, Lee D.; Fan, Cheng; Parvez, Masood; Piers, Warren E.
Organometallics, 2009 , vol. 28, # 1 p. 249 - 263
