9-硼二环[3.3.1]壬烷 二聚物合成路线 （共 39 条）
反应条件
in 1,2,5-trimethyl-benzene byproducts: H2, PH3; heating in mesitylene at 130°C for 60 min under exclusion of air and moisture; monitored by NMR;
参考文献
Koester, Roland; Schuessler, Wilhelm; Synoradzki, Ludwik
Chemische Berichte, 1987 , vol. 120, p. 1105 - 1116
反应条件
in 1,2,5-trimethyl-benzene byproducts: H2, PH3; heating in mesitylene at 130°C under exclusion of air and moisture;
参考文献
Koester, Roland; Schuessler, Wilhelm; Synoradzki, Ludwik
Chemische Berichte, 1987 , vol. 120, p. 1105 - 1116
反应条件
in tetrahydrofuran addn. of NaOCH3 to a soln. of the B-compound in THF at -78°C, soln. was warmed to room temp. in ca. 2 h; detected by B-NMR;
参考文献
Koester, Roland; Seidel, G.; Blaeser, Dieter; Boese, Roland
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994 , vol. 49, # 3 p. 370 - 376
反应条件
in toluene byproducts: H2; stirring at 20°C for 5 h under exclusion of air and moisture; monitored by IR;
参考文献
Chemische Berichte, , vol. 120, p. 1117 - 1124
反应条件
in 1,2,5-trimethyl-benzene byproducts: H2; heating in mesitylene at 130-150°C under exclusion of air and moistur, further products: Ph2PH, Ph2P(O)PPh2; evapn. of mesitylene and Ph2PH in vacuum, sublimation of a product-mixture, product Ph2POBC8H14-HBC8H14 elem. anal.;
参考文献
Koester, Roland; Schuessler, Wilhelm; Synoradzki, Ludwik
Chemische Berichte, 1987 , vol. 120, p. 1105 - 1116
反应条件
acetophenone in tetrahydrofuran Kinetics; 25°C; detected by IR;
参考文献
Brown, Herbert C.; Wang, Kung K.; Chandrasekharan, J.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2340 - 2343
反应条件
in toluene Schlenk technique, under Ar; soln. of (C8H14BH)2 (0.5 equiv.) and HOTf refluxed for 1 h;
参考文献
Schulenberg, Nikola; Wadepohl, Hubert; Himmel, Hans-Joerg
Angewandte Chemie - International Edition, 2011 , vol. 50, # 44 p. 10444 - 10447
反应条件
in toluene dropping BBr3 to soln. of bis-9-borabicyclo(3,3,1)nonane at 80-120°C, stirring at 100°C for 30 min; evapn.;
参考文献
Koester, R.; Grassberger, M. A.
Liebigs Annalen der Chemie, 1968 , vol. 719, p. 169 - 186
Full Text Show Details
Gmelin Handbook: B: B-Verb.9, 6.3.2, page 303 - 314
反应条件
in benzene-d6 in NMR tube, 15 min; not isolated, detected by NMR;
参考文献
Noeth, H.; Staudigl, R.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 481, p. 41 - 50
参考文献
Koester, R.; Grassberger, M. A.
Liebigs Annalen der Chemie, 1968 , vol. 719, p. 169 - 186
Full Text Show Details
Gmelin Handbook: B: B-Verb.9, 6.3.2, page 303 - 314
