您好，欢迎来到魔法化学网！
合作交流
|
服务时间(9:30-18:00)
百科
百科
▼
百科
资讯
搜索
结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
首页
化合物百科
价格行情
资讯
化工导航
实验室工具
搜索
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-苯基二苯甲酮
合成路线
（共 109 条）
90-90-4
4-溴苯甲酰苯
+
98-80-6
苯硼酸
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
trans-[Ni(Naph)Cl(PPh3)2]; PCy3*HBF4; potassium carbonate in water; toluene T=20°C; Suzuki-Miyaura cross-coupling reaction; 24 h; Inert atmosphere;
参考文献
Fan, Xin-Heng; Yang, Lian-Ming
European Journal of Organic Chemistry, 2011 , # 8 p. 1467 - 1471
134-85-0
4-氯二苯甲酮
+
98-80-6
苯硼酸
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
tripotassium phosphate monohydrate; 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; palladium diacetate in 1,4-dioxane T=135°C; Suzuki-Miyaura coupling; 24 h; Inert atmosphere;
参考文献
Wong, Shun Man; So, Chau Ming; Chung, Kin Ho; Lau, Chak Po; Kwong, Fuk Yee
European Journal of Organic Chemistry, 2012 , # 22 p. 4172 - 4177
143-66-8
四苯硼钠
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
palladium diacetate; sodium carbonate in water T=20°C; Suzuki-Miyaura coupling; 0.333333 h;
参考文献
Zarei, Amin; Khazdooz, Leila; Hajipour, Abdol R.; Rafiee, Fatemeh; Azizi, Ghobad; Abrishami, Fatemeh
Tetrahedron Letters, 2012 , vol. 53, # 4 p. 406 - 408
960-16-7
三丁基苯基锡
+
134-85-0
4-氯二苯甲酮
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
tris(dibenzylideneacetone)dipalladium (0); P(N(CH2Ph)CH2CH2)3N; cesium fluoride in 1,4-dioxane T=60°C; Stille cross-coupling; 28 h;
参考文献
Su, Weiping; Urgaonkar, Sameer; McLaughlin, Patrick A.; Verkade, John G.
Journal of the American Chemical Society, 2004 , vol. 126, # 50 p. 16433 - 16439
5122-94-1
4-联苯硼酸
+
65-85-0
苯甲酸
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
1: benzoic acid With potassium phosphate in 1,4-dioxane T=20°C; 0.0833333 h; Inert atmosphere; 2: With DMEG in 1,4-dioxane T=20°C; 2 h; Inert atmosphere; 3: 1,1'-Biphenyl-4-yl-boronic acid With tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=90°C; 16 h; Inert atmosphereSealed tube;
参考文献
Pathak, Arunendra; Rajput, Chatrasal S.; Bora, Pushkar S.; Sharma, Somesh
Tetrahedron Letters, 2013 , vol. 54, # 17 p. 2149 - 2150
108-86-1
溴代苯
+
134-85-0
4-氯二苯甲酮
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
1: bromobenzene With lithium 2: With zinc(II) chloride 3: 4-chlorobenzophenone With nickel phosphine amido pincer complex in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=70°C; Negishi cross-coupling; 6 h; Further stages.;
参考文献
Wang, Li; Wang, Zhong-Xia
Organic Letters, 2007 , vol. 9, # 21 p. 4335 - 4338
98-80-6
苯硼酸
+
92-92-2
4-苯基苯甲酸
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
1: 1,1'-biphenyl-4-carboxylic acid With potassium phosphate in 1,4-dioxane T=20°C; 0.0833333 h; Inert atmosphere; 2: With DMEG in 1,4-dioxane T=20°C; 2 h; Inert atmosphere; 3: 3,4,5-trimethoxyphenylboronic acid With tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=90°C; 16 h; Inert atmosphereSealed tube;
参考文献
Pathak, Arunendra; Rajput, Chatrasal S.; Bora, Pushkar S.; Sharma, Somesh
Tetrahedron Letters, 2013 , vol. 54, # 17 p. 2149 - 2150
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
SIDip*HCl; palladium diacetate in tetrahydrofuran T=23°C; Sizuki-Miyaura cross coupling; 3 h;
参考文献
Andrus; Song
Organic letters, 2001 , vol. 3, # 23 p. 3761 - 3764
90-90-4
4-溴苯甲酰苯
+
603-33-8
三苯基铋
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
potassium phosphate; triphenylphosphine; palladium diacetate in N,N-dimethyl-formamide T=90°C; 1 h;
参考文献
Rao, Maddali L.N.; Banerjee, Debasis; Jadhav, Deepak N.
Tetrahedron Letters, 2007 , vol. 48, # 15 p. 2707 - 2711
6136-66-9
4-碘二苯酮
+
100-59-4
苯基氯化镁
→
反应条件
2128-93-0
4-苯基二苯甲酮
反应条件
1: phenyl-magnesium chloride in tetrahydrofuran; ethylene glycol dimethyl ether T=-20°C; 0.166667 h; 2: 4-PhCOC6H4I With iron (III) acetylacetonate in tetrahydrofuran; ethylene glycol dimethyl ether T=-20 - 25°C; 4 h;
参考文献
Sapountzis, Ioannis; Lin, Wenwei; Kofink, Christiane C.; Despotopoulou, Christina; Knochel, Paul
Angewandte Chemie - International Edition, 2005 , vol. 44, # 11 p. 1654 - 1657
1
2
3
4
...
11
下一页
末页
到第
页
确定
