(S)-2-异丁基琥珀酸-1-甲酯合成路线 (共 2 条)
反应条件
chiral (1,1'-ferrocenediyl)bis(phospholo[3,4-d][1,3]dioxole); hydrogen; rhodium cation in methanol T=20°C; P=4137.29 Torr; 12 h; Title compound not separated from byproducts.;
参考文献
Organic Letters, , vol. 4, # 25 p. 4471 - 4474
反应条件
potassium tert-butylate; hydrogen; sodium methylate; lt;(S,S)-(iPr-BPE)Rh(cod)gt;BF4 1.) tert-BuOH, 50 deg C, 2 h; r.t., overnight, 2.) MeOH, 5.5. bar, r.t., 3 h; Multistep reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 37, # 13-14 p. 1931 - 1933