N-(3,4-二氢萘-1-基)乙酰胺合成路线 (共 2 条)
反应条件
hydrogen; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate; (Sa)-monophos in dichloromethane
T=20°C; P=11251.1 Torr; 20 h;
参考文献
Dydio, Pawel; Rubay, Christophe; Gadzikwa, Tendai; Lutz, Martin; Reek, Joost N. H.
Journal of the American Chemical Society, 2011 , vol. 133, # 43 p. 17176 - 17179
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; C55H31BF22N2O2P(1-)*C16H36N(1+); hydrogen; triphenylphosphine in ethyl acetate
T=20°C; P=15001.5 Torr; 4 h; Inert atmosphereSchlenk technique; Reagent/catalystSolvent; enantioselective reaction;
参考文献
Frank, Dominik J.; Franzke, Axel; Pfaltz, Andreas
Chemistry - A European Journal, 2013 , vol. 19, # 7 p. 2405 - 2415