in tetrahydrofuran byproducts: CO; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)6(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
参考文献
Lee, K. Y.; Kuchynka, D. J.; Kochi, J. K.
Organometallics, 1987 , vol. 6, p. 1886 - 1897
tetrahydrofuran in tetrahydrofuran byproducts: CO; 5-mL aliquot of 1E-2 M Mn(CO)4P(OPh)3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)6(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
in tetrahydrofuran byproducts: CO; 5-mL aliquot of 1E-2 M Mn(CO)4PPh3(1-) in THF added under Ar to 5 mL of 1E-2 M Mn(CO)6(1+) in THF at 22°C, react. complete within 5 min; not isolated; detected by IR;
