2-(二甲氨基)-2′-溴-1,1′-联苯合成路线 (共 2 条)
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water T=110°C; Suzuki coupling; Inert atmosphere; regioselective reaction;
参考文献
Dunkel, Petra; Turos, Gyoergy; Benyei, Attila; Ludanyi, Krisztina; Matyus, Peter
Tetrahedron, 2010 , vol. 66, # 13 p. 2331 - 2339
反应条件
n-butyllithium 1.) ether, hexane, -78 deg C, 30 min, 2.) ether, hexane, RT, 17 h; Yield givenMultistep reaction;
参考文献
Aranyos, Attila; Old, David W.; Kiyomori, Ayumu; Wolfe, John P.; Sadighi, Joseph P.; Buchwald, Stephen L.
Journal of the American Chemical Society, 1999 , vol. 121, # 18 p. 4369 - 4378