3-甲基-2-环己烯-1-醇合成路线 （共 78 条）
反应条件
1: 95 percent / pyridine / 1.) acetone-solid CO2 bath, 30 min; 2.) 20 deg C, 30 min
2: formamide / 4 h / 55 °C
View Scheme
参考文献
Knight, Derek J.; Whitham, Gordon H.; Williams, Jonathan G.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 2149 - 2152
反应条件
n-butyllithium; (S)-(+)-1-(2-pyrrolidinylmethyl)-pyrrolidine in hexane
T=30°C; 72 h; Yield given;
参考文献
Hansson, Maria; Arvidsson, Per I.; Nilsson Lill, Sten O.; Ahlberg, Per
Journal of the Chemical Society, Perkin Transactions 2, 2002 , # 4 p. 763 - 767
反应条件
D-glucopyranose; nicotinamide adenine dinucleotide phosphate in aq. phosphate buffer
T=25°C; pH=7 - 8; 21 h; Enzymatic reaction; stereoselective reaction;
参考文献
Roiban, Gheorghe-Doru; Agudo, Ruben; Reetz, Manfred T.
Tetrahedron, 2013 , vol. 69, # 26 p. 5306 - 5311
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane
4.5 h; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Roiban, Gheorghe-Doru; Agudo, Ruben; Reetz, Manfred T.
Tetrahedron, 2013 , vol. 69, # 26 p. 5306 - 5311
反应条件
3,3-dimethyldioxirane in acetone
Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Murray, Robert W.; Singh, Megh; Williams, Brian L.; Moncrieff, Hazel M.
Journal of Organic Chemistry, 1996 , vol. 61, # 5 p. 1830 - 1841
反应条件
potassium hydride
1. THF, 25 grad C 2. CCl4, 80 grad C, 43 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Knapp; Patel
Tetrahedron Letters, 1982 , vol. 23, # 35 p. 3539 - 3542
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane
T=20°C; 16 h; Inert atmosphere;
参考文献
Kelly, Brendan D.; Allen, Julia M.; Tundel, Rachel E.; Lambert, Tristan H.
Organic Letters, 2009 , vol. 11, # 6 p. 1381 - 1383
反应条件
pyridine; phosphorus tribromide
参考文献
Vig,O.P. et al.
Indian Journal of Chemistry, 1968 , vol. 6, p. 188 - 190
