(1-戊基)三苯基溴化磷合成路线 （共 78 条）
参考文献
Genard, S.; Patin, H.
Bulletin de la Societe Chimique de France, 1991 , # 3 p. 397 - 406
反应条件
1: NaH / dimethylsulfoxide / 1 h / 20 °C 2: dimethylsulfoxide / 12 h / 20 °C 3: 1.30 g / m-chloroperbenzoic acid; K2CO3 / CH2Cl2 / 3 h 4: 76 percent / aq. H2SO4 / tetrahydrofuran View Scheme
参考文献
Steinreiber, Andreas; Mayer, Sandra F.; Saf, Robert; Faber, Kurt
Tetrahedron Asymmetry, 2001 , vol. 12, # 10 p. 1519 - 1528
反应条件
1: NaOEt / tetrahydrofuran / 1 h / 25 °C 2: n-BuLi / toluene / 2 h / 25 °C 3: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: (i) Na<N(SiMe3)2>, THF, (ii) /BRN= 1746480/ 2: 9-BBN / tetrahydrofuran View Scheme
参考文献
Bestmann; Kantardjiew; Roesel; et al.
Chemische Berichte, 1978 , vol. 111, # 1 p. 248 - 253
参考文献
Schlosser,M. et al.
Helvetica Chimica Acta, 1974 , vol. 57, p. 1567 - 1576
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 60 min, 2.) -78 deg C, 30 min; 20 deg C, 12 h 2: 60 percent / HCl / H2O; acetone / 0.5 h / 20 °C View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1.1: sodium amide / tetrahydrofuran / 4 h / Heating 1.2: tetrahydrofuran / -78 °C 2.1: mCPBA / diethyl ether / 1 h / 20 °C 2.2: aq. HCl / tetrahydrofuran / 2 h / 20 °C 3.1: NaClO2; NaH2PO4; 2-methyl-2-butene / 2-methyl-propan-2-ol / 24 h / 20 °C 4.1: 1.13 g / PhSO2Cl; pyridine 5.1: 99 percent / H2 / Pd/C View Scheme
参考文献
Dirat; Kouklovsky; Langlois, Yves
Organic Letters, 1999 , vol. 1, # 5 p. 753 - 755
反应条件
1.1: sodium amide / tetrahydrofuran / 4 h / Heating 1.2: tetrahydrofuran / -78 °C 2.1: mCPBA / diethyl ether / 1 h / 20 °C 2.2: aq. HCl / tetrahydrofuran / 2 h / 20 °C 3.1: NaClO2; NaH2PO4; 2-methyl-2-butene / 2-methyl-propan-2-ol / 24 h / 20 °C 4.1: 1.13 g / PhSO2Cl; pyridine 5.1: 99 percent / H2 / Pd/C 6.1: 93 percent / triphenylphosphine; DIAD / tetrahydrofuran / 3 h / 20 °C View Scheme
参考文献
Dirat; Kouklovsky; Langlois, Yves
Organic Letters, 1999 , vol. 1, # 5 p. 753 - 755
反应条件
(i) K, HMPT, (ii) /BRN= 1769505/; Multistep reaction;
参考文献
Bestmann; Stransky; Vostrowsky; Range
Chemische Berichte, 1975 , vol. 108, # 11 p. 3582 - 3595
反应条件
1: n-pentyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: pelargonaldehyde in tetrahydrofuran; hexane T=20°C; Wittig Olefination; 2.5 h;
参考文献
Willand-Charnley, Rachel; Dussault, Patrick H.
Journal of Organic Chemistry, 2013 , vol. 78, # 1 p. 42 - 47
