2,3,5,6-四甲基苯乙酮合成路线 （共 29 条）
反应条件
acetic anhydride; aluminium trichloride T=35°C; 30 h; Further byproducts given;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 830 - 837
反应条件
aluminium trichloride in chloroform T=18°C; 6 h; further solvents, times, temperatures, methyl substituted acetophenones and benzenes; Product distributionMechanism;
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 3001 - 3012
反应条件
aluminium trichloride in chloroform T=18°C; 6 h; further solvents, times, temperatures, methyl substituted acetophenones and benzenes; Product distributionMechanism;
参考文献
Andreou, Andreas D.; Bulbulian, Roger V.; Gore, Peter H.
Journal of Chemical Research, Miniprint, 1980 , # 7 p. 3001 - 3012
反应条件
aluminium trichloride in chloroform T=18°C; 6 h; further solvents, times, temperatures, methyl substituted acetophenones and benzenes; Product distributionMechanism;
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 3001 - 3012
反应条件
1: AlCl3, aluminium chloride; sodium chloride / water / 2 h / 100 °C
2: bromine; potassium hydroxide / 1,4-dioxane; water / 2 h / 0 - 20 °C / Reflux
View Scheme
参考文献
Moorthy, Jarugu Narasimha; Senapati, Kalyan; Parida, Keshaba Nanda; Jhulki, Samik; Sooraj, Kunnikuruvan; Nair, Nisanth N.
Journal of Organic Chemistry, 2011 , vol. 76, # 23 p. 9593 - 9601
反应条件
nitric acid; acetic anhydride
T=0°C; 2 h;
参考文献
Keumi, Takashi; Morita, Toshio; Teramoto, Koichi; Takahashi, Hisakazu; Yamamoto, Hiroshi; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3439 - 3446
反应条件
sulfuric acid; nitric acid in chloroform
参考文献
Tajana; Rossi; Salvaterra
Arzneimittel-Forschung, 1971 , vol. 21, # 11 p. 1661 - 1662
反应条件
nitric acid; acetic anhydride
T=0°C; 2 h; var. polymethylacetophenones; Product distributionMechanism;
参考文献
Keumi, Takashi; Morita, Toshio; Teramoto, Koichi; Takahashi, Hisakazu; Yamamoto, Hiroshi; et al.
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3439 - 3446
反应条件
copper(ll) bromide in dichloromethane
参考文献
Hori, Mikio; Kataoka, Tadashi; Shimizu, Hiroshi; Imai, Eiji; Matsumoto, Yukiharu; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987 , p. 1211 - 1220
