1-甲氧基-1,3-环己二烯合成路线 （共 48 条）
反应条件
in dichloromethane 1 h; Ambient temperature;
参考文献
Pindur, Ulf; Keilhofer, Diana
Liebigs Annalen der Chemie, 1993 , # 9 p. 947 - 954
反应条件
1: 84 percent / 336 h / 200 - 210 °C 2: 100 percent / LiAlH4 / diethyl ether / 4 h / Heating 3: 93 percent / PBr3 / diethyl ether / 3 h / Heating 4: 91 percent / LiAlH4 / diethyl ether / 18 h / Heating 5: 46 percent / HNO3 / CH2Cl2 / 1 h / 25 °C 6: 79 percent / H2 / 10 percent Pd/C / methanol / 25 °C / 800 - 900 Torr View Scheme
参考文献
Knoelker, Hans-Joachim; Hopfmann, Thomas
Tetrahedron, 2002 , vol. 58, # 44 p. 8937 - 8945
反应条件
hydrogen; phenanthrene chrome tricarbonyle in cyclohexane T=80°C; P=5320 Torr; 28 h; var. solvents, times; Product distribution;
参考文献
Maux, P.Le; Dabard, R.; Simonneaux, G.
Journal of Organometallic Chemistry, 1983 , vol. 241, # 1 p. 37 - 44
反应条件
1: 96 percent / benzene / 1.5 h / Heating 2: 76 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 0.5 h 3: 71 percent / 0.5 h / 140 °C 4: 64 percent / aq. NaOH View Scheme
参考文献
Giles,R.G.F.; Roos,G.H.P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 1632 - 1635
反应条件
1: 30 percent / 96 h / 130 °C 2: 86 percent / lithium aluminum hydride / diethyl ether / 2 h / Heating 3: 97 percent / phosphorus tribromide / CH2Cl2 / 4 h / Heating 4: 79 percent / lithium aluminum hydride / toluene / 0.5 h / Heating 5: 43 percent / conc. HNO3; conc. H2SO4 / CH2Cl2 / 1 h / 20 °C 6: 88 percent / H2 / Pd/C / methanol / 800 - 900 Torr View Scheme
参考文献
Tetrahedron, , vol. 55, # 34 p. 10391 - 10412
反应条件
toluene-4-sulfonic acid
参考文献
Emery, Sadie L.; Fies, Carmen H.; Hester, Evan J.; McClusky, John V.
Journal of Organic Chemistry, 1999 , vol. 64, # 11 p. 3788 - 3789
反应条件
1: 200 °C 2: Hydrolysis View Scheme
参考文献
Birch; Hextall
Australian Journal of Chemistry, 1955 , vol. 8, p. 96,99
参考文献
Journal of the American Chemical Society, , vol. 81, p. 3658,3661, 3662, 3665
反应条件
2: NaOMe
3: Ag2O
4: 150 °C / 0.5 Torr
View Scheme
参考文献
Birch,A.J. et al.
Journal of the Chemical Society, 1964 , p. 2941 - 2944
反应条件
1: benzene / 4 h / Heating
2: 1.) K2CO3, 2.) pyridiene / 1.) acetone, reflux, 2 h, 2.) acetone, reflux, 3 h
3: 90 percent / 0.67 h / Heating
4: 10 percent / boron trifluoride etherate / 60 °C
View Scheme
参考文献
Hugo; Nicholson; Snijman
Synthetic Communications, 1994 , vol. 24, # 1 p. 23 - 28
