1H,1H,2H-全氟-1-癸烯合成路线 （共 37 条）
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9-10 ;
反应条件
1: 100 percent Chromat. / AIBN / 8 h / 75 °C 2: 96.5 percent Chromat. / TBAF / tetrahydrofuran / 0.08 h / 65 °C View Scheme
参考文献
Organic Letters, , vol. 2, # 15 p. 2347 - 2349
反应条件
1: 1H-tetrazole / acetonitrile / 0 - 20 °C / Inert atmosphere 2: 3-chloro-benzenecarboperoxoic acid / dichloromethane; acetonitrile / -40 - 20 °C / Inert atmosphere 3: ammonium formate; zinc / tetrahydrofuran; acetonitrile / 2 h / 20 °C / Inert atmosphere View Scheme
参考文献
Organic Letters, , vol. 13, # 7 p. 1824 - 1827
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 7-8 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
silver(l) oxide T=80 - 120°C; 1 - 4 h; Product distribution / selectivity;
参考文献
US2007/123731 A1, ;
Page/Page column 3-4 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
potassium hydroxide T=100°C; 4 h; Product distribution / selectivity;
参考文献
US2007/123731 A1, ;
Page/Page column 6 ;
→
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
反应条件
tetrabutyl ammonium fluoride; acetic acid in tetrahydrofuran T=65°C; Elimination; 0.5 h; Product distribution;
参考文献
Organic Letters, , vol. 2, # 15 p. 2347 - 2349
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
T=100°C; 4 h; Product distribution / selectivity;
参考文献
US2007/123731 A1, ;
Page/Page column 6 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 6-7; 8-9 ;
