1H,1H,2H-全氟-1-癸烯合成路线 （共 37 条）
反应条件
acetone T=20°C; Addition; 72 h; Irradiation;
参考文献
Cirkva, Vladimir; Boehm, Stanislav; Paleta, Oldrich
Journal of Fluorine Chemistry, 2000 , vol. 102, # 1-2 p. 159 - 168
反应条件
hydrogen; palladium on activated charcoal in diethyl ether
T=25°C; P=750.06 Torr; 6 h; ultrasound;
参考文献
Carcenac; Tordeux; Wakselman; Diter
Journal of Fluorine Chemistry, 2005 , vol. 126, # 9-10 p. 1347 - 1355
反应条件
perfluorobutyl tetrahydrofuran; perfluoropropyltetrahydropyran
T=140°C; 3 h;
参考文献
Wlassics, Ivan; Barchiesi; Sala
Journal of Fluorine Chemistry, 2003 , vol. 123, # 1 p. 119 - 126
反应条件
1: 80 percent / Br2, Hg(OAc)2 / Ambient temperature
2: 95 percent / NaOH / H2O / 1.) 0 deg C; 2.) r.t., 1 h; 3.) 40 deg C, 0.5 h
3: 70 percent / t-BuOK / tetrahydrofuran / 1.) -10 deg C; 2.) r.t.
View Scheme
参考文献
Coudures, C.; Pastor, R.; Cambon, A.
Journal of Fluorine Chemistry, 1984 , vol. 24, p. 93 - 104
反应条件
1: 89 percent / chlorine / neat (no solvent) / Irradiation
2: 1.) zinc; 2.) HCl / 1.) DMF, 100 deg C, 1 h
View Scheme
参考文献
Burton, Donald J.; Spawn, Terence D.
Journal of Fluorine Chemistry, 1988 , vol. 38, p. 119 - 124
反应条件
bromine in tetrachloromethane
T=120°C;
参考文献
Santini,G. et al.
Tetrahedron, 1973 , vol. 29, p. 2411 - 2414
反应条件
ozone in neat (no solvent)
T=60°C; 1 h;
参考文献
Caminade, Anne-Marie; Blanc, Maurice Le; Khatib, Fayez El; Koenig, Max
Tetrahedron Letters, 1985 , vol. 26, # 24 p. 2889 - 2890
