(E,E)-2,4-十二碳二烯醛合成路线 （共 13 条）
反应条件
manganese(IV) oxide in dichloromethane 2 h;
参考文献
Wang, Yonghui; Ma, Jianguo; Cheon, Hwan-Sung; Kishi, Yoshito
Angewandte Chemie - International Edition, 2007 , vol. 46, # 8 p. 1333 - 1336
反应条件
cyclohexylamine; lithium diisopropyl amide in tetrahydrofuran T=0 - 25°C; 3 h;
参考文献
Journal of Organic Chemistry, , vol. 55, # 19 p. 5312 - 5323
反应条件
palladium diacetate; triphenylphosphine in toluene T=110°C; 0.5 h; Inert atmosphere;
参考文献
Tang, Xiang-Ying; Shi, Min
Tetrahedron, 2009 , vol. 65, # 43 p. 8863 - 8868
反应条件
Caprylic Aldehyde; lithium diisopropyl amide in tetrahydrofuran T=0 - 25°C; 3 h;
参考文献
Journal of Organic Chemistry, , vol. 55, # 19 p. 5312 - 5323
反应条件
1: LDA / tetrahydrofuran / -78 - 20 °C 2: Dibal-H 3: MnO2 View Scheme
参考文献
Organic Letters, , vol. 9, # 2 p. 319 - 322
反应条件
lithium diisopropyl amide in tetrahydrofuran T=0 - 25°C; other base, substrates, aldehydes, ketones; stereoselectivity; Product distributionMechanism;
参考文献
Kann, Nina; Rein, Tobias; Akermark, Bjoern; Helquist, Paul
Journal of Organic Chemistry, 1990 , vol. 55, # 19 p. 5312 - 5323
反应条件
1: 1. lithium diisopropylamine (LDA) / 1. THF, -50 deg C, 15min, 2. THF, 1h, -80 deg C 2: potassium t-butoxide (KOt-Bu) / tetrahydrofuran / 4 °C 3: tetrabutylammonium fluoride trihydrate (TBAF) / tetrahydrofuran / 1 h / 0 °C 4: 17 percent / 36percent aq. HCl / tetrahydrofuran / 48 h View Scheme
参考文献
Tetrahedron, , vol. 46, # 20 p. 7301 - 7312
反应条件
1: tetrabutylammonium fluoride trihydrate (TBAF) / tetrahydrofuran / 1 h / 0 °C 2: 17 percent / 36percent aq. HCl / tetrahydrofuran / 48 h View Scheme
参考文献
Tetrahedron, , vol. 46, # 20 p. 7301 - 7312
反应条件
hydrogenchloride in methanol 2.25 h;
参考文献
Tetrahedron, , vol. 46, # 20 p. 7301 - 7312
反应条件
1: Dibal-H 2: MnO2 View Scheme
参考文献
Organic Letters, , vol. 9, # 2 p. 319 - 322
