N,N,2-三甲基丙酰胺合成路线 （共 43 条）
反应条件
1: N-(tert-butyldimethylsilyl)-2-buten-1-amine With n-butyllithium in tetrahydrofuran; benzene
T=60°C; 1 h;
2: N,N-dimethyl-2-methylpropionamide in benzene
T=20°C; 2 h; Further stages.;
参考文献
Jacobson, Madeleine A.; Williard, Paul G.
Journal of Organic Chemistry, 2002 , vol. 67, # 1 p. 32 - 37
反应条件
triethylammonium tetrakis(pentafluorophenyl)-borate; diethylesilane; (2,6-bis(di-tert-butylphosphinito)phenyl)Ir(H)(SiEt2H); (2,6-bis(di-tert-butylphosphinito)phenyl)Ir(H)3(SiEt2H); hydrogen in benzene-d6
T=60°C; P=760.051 Torr; 0.4 h;
参考文献
Park, Sehoon; Brookhart, Maurice
Journal of the American Chemical Society, 2012 , vol. 134, # 1 p. 640 - 653
反应条件
1: N,N-dimethyl-2-methylpropionamide With trifluoromethylsulfonic anhydride in dichloromethane
T=-15°C; 0.166667 h;
2: 4-chloro-1-ethenylbenzene With 2,3,5-trimethyl-pyridine
4 h; Heating;
参考文献
Chen, Bang-Chi; Ngu, Khehyong; Guo, Peng; Liu, Wen; Sundeen, Joseph E; Weinstein, David S; Atwal, Karnail S; Ahmad, Saleem
Tetrahedron Letters, 2001 , vol. 42, # 36 p. 6227 - 6229
