二甲基[二(苯基乙炔基)]硅烷合成路线 （共 15 条）
反应条件
CpZrEt2; iodine Yield given. Multistep reaction;
参考文献
Takahashi, Tamotsu; Xi, Zhenfeng; Obora, Yasushi; Suzuki, Noriyuki
Journal of the American Chemical Society, 1995 , vol. 117, # 9 p. 2665 - 2666
反应条件
1: bis(phenylethynyl)dimethylsilane With Li-naphthalenide in tetrahydrofuran
T=20°C; Cyclization; Metallation; 0.166667 h;
2: With zinc(II) chloride−TMEDA; triphenyl-silyl chloride in tetrahydrofuran
T=-78 - 20°C; Substitution; 1.5 h;
3: bromobenzene With bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
Arylation; 12 h; Heating; Further stages.;
参考文献
Yamaguchi, Shigehiro; Endo, Tomonori; Uchida, Manabu; Izumizawa, Takenori; Furukawa, Kenji; Tamao, Kohei
Chemistry - A European Journal, 2000 , vol. 6, # 9 p. 1683 - 1692
参考文献
Boydston, Andrew J.; Yin, Youshi; Pagenkopf, Brian L.
Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10350 - 10354
反应条件
1: With naphthalenyllithium in tetrahydrofuran
T=20°C; 0.5 h;
2: With zinc(II) chloride in tetrahydrofuran
T=-10°C; 0.333333 h;
参考文献
Boydston, Andrew J.; Yin, Youshi; Pagenkopf, Brian L.
Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10350 - 10354
反应条件
in toluene
N2 atmosphere, stirring (room temp., 48 h); filtration, reduction of volume, pptn. (hexanes); elem. anal.;
参考文献
Mezailles, Nicolas; Ricard, Louis; Mathey, Francois; Le Floch, Pascal
European Journal of Inorganic Chemistry, 1999 , # 12 p. 2233 - 2241
