(9E)-7,8-二氢-10-阿朴-beta-胡萝卜素-10-基甲酸酯合成路线 （共 8 条）
反应条件
selenium(IV) oxide; dihydrogen peroxide in 1,1-dimethylpropan-1-ol T=0°C; Baeyer-Villiger oxidation;
参考文献
Ohmiya, Yoshihiro; Kojima, Satoshi; Nakamura, Mitsuhiro; Niwa, Haruki
Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 7 p. 1197 - 1205
反应条件
1: 76 percent / LiHMDS / tetrahydrofuran / 5 h / Heating 2: 100 percent / DIBALH / toluene / 0 °C 3: 95 percent / MnO2 / CH2Cl2 / 2 h / 20 °C 4: 45 percent / SeO2; H2O2 / 2-methyl-butan-2-ol / 0 °C View Scheme
参考文献
Burford, Clifford; Cooke, Frank; Roy, Glenn; Magnus, Philip
Tetrahedron, 1983 , vol. 39, # 6 p. 867 - 876
反应条件
1: 95 percent / MnO2 / CH2Cl2 / 2 h / 20 °C 2: 45 percent / SeO2; H2O2 / 2-methyl-butan-2-ol / 0 °C View Scheme
参考文献
Kojima, Satoshi; Maki, Shojiro; Hirano, Takashi; Ohmiya, Yoshihiro; Niwa, Haruki
Tetrahedron Letters, 2000 , vol. 41, # 22 p. 4409 - 4413
反应条件
1: 100 percent / DIBALH / toluene / 0 °C 2: 95 percent / MnO2 / CH2Cl2 / 2 h / 20 °C 3: 45 percent / SeO2; H2O2 / 2-methyl-butan-2-ol / 0 °C View Scheme
参考文献
Kojima, Satoshi; Maki, Shojiro; Hirano, Takashi; Ohmiya, Yoshihiro; Niwa, Haruki
Tetrahedron Letters, 2000 , vol. 41, # 22 p. 4409 - 4413
反应条件
T=20°C; 0.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Burford, Clifford; Cooke, Frank; Roy, Glenn; Magnus, Philip
Tetrahedron, 1983 , vol. 39, # 6 p. 867 - 876
反应条件
Latia luciferase; purple protein; oxygen
参考文献
Nakamura, Mitsuhiro; Masaki, Mizuki; Maki, Shojiro; Matsui, Ryo; Hieda, Minako; Mamino, Masashi; Hirano, Takashi; Ohmiya, Yoshihiro; Niwa, Haruki
Tetrahedron Letters, 2004 , vol. 45, # 10 p. 2203 - 2205
反应条件
1: O2; Latia luciferase; purple protein
2: 91 percent / LiHMDS / tetrahydrofuran
3: 80 percent / p-TsOH / acetone; H2O
View Scheme
参考文献
Nakamura, Mitsuhiro; Masaki, Mizuki; Maki, Shojiro; Matsui, Ryo; Hieda, Minako; Mamino, Masashi; Hirano, Takashi; Ohmiya, Yoshihiro; Niwa, Haruki
Tetrahedron Letters, 2004 , vol. 45, # 10 p. 2203 - 2205
反应条件
1: O2; Latia luciferase; purple protein
2: 91 percent / LiHMDS / tetrahydrofuran
3: 80 percent / p-TsOH / acetone; H2O
View Scheme
参考文献
Nakamura, Mitsuhiro; Masaki, Mizuki; Maki, Shojiro; Matsui, Ryo; Hieda, Minako; Mamino, Masashi; Hirano, Takashi; Ohmiya, Yoshihiro; Niwa, Haruki
Tetrahedron Letters, 2004 , vol. 45, # 10 p. 2203 - 2205
