四(乙腈)四氟硼酸钯(II)合成路线 （共 6 条）
反应条件
in acetonitrile under Ar; Pd sponge, NOBF4 were added to dried acetonitrile and stirred for 24 h at 25°C; the soln. was filtered into dried (CH3CH2)2O, the ppt. was washed with dried 9C2H5)2O, dried in vac.; elem. anal.;
参考文献
Organometallics, , vol. 20, # 13 p. 2697 - 2703
反应条件
acetonitrile in acetonitrile byproducts: NO; under vac., stirring Pd and NOBF4 in MeCN, periodically removal of NO, stirring (12 h); filtn., pptn. on addn. of Et2O, washing (Et2O), drying (vac.); elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 567 - 588
反应条件
acetonitrile in acetonitrile byproducts: AgCl; under vac. or N2, stirring PdCl2 and AgBF4 in MeCN (30 min); filtn., concn. of filtrate (vac.), pptn. on addn. of Et2O, recrystn. (MeCN/Et2O);
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 567 - 588
反应条件
in acetonitrile Electrochem. Process; Pd(CH3CO2)2 in MeCN reacted with N((CH2)3CH3)4BF4 in divided cell (Pt)-(Pt) at room temp., 10 mA;
参考文献
Journal of the American Chemical Society, , vol. 129, # 8 p. 2246 - 2247
反应条件
1.5 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 15, # 1 p. 112 - 115
反应条件
in diethyl ether; acetonitrile byproducts: acetic acid; stirring (room temp.); redissoln. of the precipitate, repptn. with Et2O; elem. anal.;
参考文献
Journal of the Chemical Society - Dalton Transactions, , # 24 p. 4733 - 4737
