N,N-二异丙基氨基硼烷合成路线 （共 54 条）
反应条件
1: tBuCH2CH2B(H)NiPr2; 4-Nitrobenzenediazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 56-57 ;
反应条件
in tetrahydrofuran for 18 h at 20°C; not isolated, detected by NMR, IR;
参考文献
Robertson, Alasdair P. M.; Leitao, Erin M.; Manners, Ian
Journal of the American Chemical Society, 2011 , vol. 133, # 48 p. 19322 - 19325
反应条件
in tetrahydrofuran T=20°C; 18 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 135, # 34 p. 12670 - 12683
反应条件
in tetrahydrofuran T=20°C; 18 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 133, # 48 p. 19322 - 19325
反应条件
in tetrahydrofuran for 18 h at 20°C; not isolated, detected by NMR;
参考文献
Robertson, Alasdair P. M.; Leitao, Erin M.; Manners, Ian
Journal of the American Chemical Society, 2011 , vol. 133, # 48 p. 19322 - 19325
反应条件
1: tBuCH2CH2B(H)NiPr2; 1-(4-chlorophenyl)diazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
WO2014/9169 A1, ;
Page/Page column 61-62 ;
反应条件
1: tBuCH2CH2B(H)NiPr2; PhN2BF4 With bis(cyclopentadienyl)titanium dichloride in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 53-54; 67-68 ;
反应条件
1: tBuCH2CH2B(H)NiPr2; n-decylmagnesium bromide in tetrahydrofuran T=0°C; 1 h; Inert atmosphere; 2: water With hydrogenchloride in tetrahydrofuran T=0°C; 0.583333 h; Inert atmosphere;
参考文献
Heterocycles, , vol. 86, # 1 p. 331 - 341
反应条件
1: tBuCH2CH2B(H)NiPr2; 4-toluenediazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; SolventReagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 53-54 ;
参考文献
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA; CLARY, Jacob, W.; SINGARAM, Bakthan
Patent: WO2013/16185 A1, 2013 ;
Location in patent: Paragraph 0102-0103 ;
