2-[(4-溴苯氧基)甲基]环氧乙烷合成路线 （共 15 条）
反应条件
potassium carbonate T=120°C; 4.5 h;
参考文献
Srivastava, Shipra; Bhandari, Kalpana; Shankar, Girija; Singh; Saxena, Anil K.
Medicinal Chemistry Research, 2004 , vol. 13, # 8-9 p. 631 - 642
反应条件
caesium carbonate in tetrahydrofuran T=50°C; 25 h; Heating / reflux;
参考文献
ASTRAZENECA AB
Patent: WO2004/16609 A1, 2004 ;
Location in patent: Page 56 ;
WO 2004/016609 A1
反应条件
tetrachloromethane; bromine
参考文献
Boeeseken
Recueil des Travaux Chimiques des Pays-Bas, 1915 , vol. 34, p. 96
Chemische Berichte, 1913 , vol. 46, p. 2616
反应条件
1: NaOH-solution 2: carbon tetrachloride; bromine View Scheme
参考文献
Boeeseken
Recueil des Travaux Chimiques des Pays-Bas, 1915 , vol. 34, p. 96
Chemische Berichte, 1913 , vol. 46, p. 2616
参考文献
Terent'ew et al.
Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 3478,3481; engl. Ausg. S. 3443
反应条件
T=20°C; Irradiationvarious times; Quantum yieldProduct distribution;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 327, # 4 p. 616 - 626
反应条件
potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in toluene T=150°C; 0.133333 h; Heating / reflux;
参考文献
ASTRAZENECA AB
Patent: WO2004/16609 A1, 2004 ;
Location in patent: Page 55 ;
WO 2004/016609 A1
反应条件
(R,R)-Co(C6H10(NCHC(COOHex)COCH3)2); diethylamine in dichloromethane T=30°C; P=15001.5 Torr; 36 h; optical yield given as percent eeenantioselective reaction;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 80, # 7 p. 1391 - 1401
反应条件
water in ethanol T=30°C; 24 h; tryptone/sucrose-supplemented minimal salt mediumMicrobiological reactionEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Molecular Catalysis B: Enzymatic, , vol. 63, # 3-4 p. 128 - 134
反应条件
(R,R)-Co(C6H10(NCHC(COOHex)COCH3)2); diethylamine in dichloromethane T=30°C; P=15001.5 Torr; 36 h; optical yield given as percent eeenantioselective reaction;
参考文献
Yamada, Wataru; Kitaichi, Yasunori; Tanaka, Hirotaka; Kojima, Tomohide; Sato, Mitsuo; Ikeno, Taketo; Yamada, Tohru
Bulletin of the Chemical Society of Japan, 2007 , vol. 80, # 7 p. 1391 - 1401
