5-叔丁基-3-甲基-1,2-苯二酚合成路线 （共 6 条）
反应条件
sulfuric acid in n-heptane T=80°C;
参考文献
Leung, Tak W.; Roth, Gary A.; Tao, Tao; Gao, Kuanqiang; Chen, Linfeng
Patent: US2010/174105 A1, 2010 ;
Location in patent: Page/Page column 7 ;
反应条件
1: With [Cu(I)(CH3CN)4]PF6; oxygen; triethylamine in dichloromethane T=-78°C; P=760.051 Torr; 8 h; Molecular sieve; 2: With toluene-4-sulfonic acid; 2-methylpropane-2-thiol in dichloromethane T=-78 - 23°C; 1 h;
参考文献
Esguerra, Kenneth Virgel N.; Fall, Yacoub; Petitjean, Laurene; Lumb, Jean-Philip
Journal of the American Chemical Society, 2014 , vol. 136, # 21 p. 7662 - 7668
反应条件
perchloric acid; sulfuric acid; hydrogen; palladium on activated charcoal 1.) EtOAc, 47 bar, 6 h, 2.) MeOH, reflux, 6 h; Yield given. Multistep reaction;
参考文献
Albrecht, Markus
Synthesis, 1996 , # 2 p. 230 - 236
反应条件
1: aq. HBr, AcOH 2: H2SO4 / acetic acid View Scheme
参考文献
Pospisil,J.; Taimr,L.
Collection of Czechoslovak Chemical Communications, 1965 , vol. 30, p. 1092 - 1103
反应条件
1: (catalytic hydrogenation) 2: aq. HBr, AcOH 3: H2SO4 / acetic acid View Scheme
参考文献
Pospisil,J.; Taimr,L.
Collection of Czechoslovak Chemical Communications, 1965 , vol. 30, p. 1092 - 1103
反应条件
acetic acid; potassium iodide
参考文献
Mueller,E. et al.
Z. Naturforsch., B: Anorg. Chem., Org. Chem., Biochem., Biophys.,, 1963 , vol. 18b, p. 1002 - 1009
