in neat (no solvent, gas phase)
Irradiation (UV/VIS); He, 200 Torr, laser-produced photolysis, irrad. at 266.2nm or 229.4nm; time-of-flight mass spectrometry;
参考文献
Penn, S. M.; Hayden, C. C.; Muyskens, K. J. Carlson; Crim, F. F.
Journal of Chemical Physics, 1988 , vol. 89, # 5 p. 2909 - 2917
Boden, J. C.; Thrush, B. A.
Proceedings of the Royal Society of London, Series A: Mathematical, Physical and Engineering Sciences, 1968 , vol. 305, p. 107 - 123
methane in gas
Kinetics; byproducts: H2O, CH3OH; under FTICR-conditions FeO(1+) is generated from Fe(1+) and N2O (1E-5 mbar), collision with Ar, react. with CH4 (0.5-2E-8 mbar);
参考文献
Schroeder, Detlef; Schwarz, Helmut
Angewandte Chemie, 1990 , vol. 102, # 12 p. 1468 - 1469
