(S)-(+)-1,2-异亚丙基甘油合成路线 (共 82 条)
反应条件
1: With lead(IV) acetate in ethyl acetate 0.583333 h; 2: With sodium tetrahydroborate in ethanol Further stages.;
参考文献
Thomas, Britt N.; Lindemann, Christopher M.; Corcoran, Robert C.; Cotant, Casey L.; Kirsch, Janet E.; Persichini, Phillip J.
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1227 - 1233
反应条件
palladium monocarbide in ethyl acetate
参考文献
Daiso Co., Ltd.
Patent: US6124479 A1, 2000 ;
反应条件
Zr(OiPr)4·HOiPr; 1,1'-binaphthyl-2,2'-diol in toluene T=20°C; 1 h;
参考文献
Dumbre, Shrinivas; Derouaux, Adeline; Lescrinier, Eveline; Piette, Andre; Joris, Bernard; Terrak, Mohammed; Herdewijn, Piet
Journal of the American Chemical Society, 2012 , vol. 134, # 22 p. 9343 - 9351
反应条件
potassium carbonate in methanol; water
参考文献
Daiso Co., Ltd.
Patent: US6143908 A1, 2000 ;
反应条件
water; sodium hydroxide in ethanol T=20 - 90°C; 1.16667 h;
参考文献
Babu, K. Chandra; Vysabhattar, Raman; Srinivas; Nigam, Satish; Madhusudhan; Mukkanti
Tetrahedron Asymmetry, 2010 , vol. 21, # 21-22 p. 2619 - 2624
反应条件
1: With ozone in methanol; dichloromethane T=-78°C; 0.333333 h; 2: With sodium tetrahydroborate in methanol; dichloromethane T=20°C; 2 h;
参考文献
Matsuura, Fumiyoshi; Peters, Rene; Anada, Masahiro; Harried, Scott S.; Hao, Junliang; Kishi, Yoshito
Journal of the American Chemical Society, 2006 , vol. 128, # 23 p. 7463 - 7465
反应条件
sodium carbonate in water
参考文献
Daiso Co., Ltd.
Patent: US6143908 A1, 2000 ;
反应条件
(R,R)-(-)-CYTOL in hexane T=20°C; 24 h;
参考文献
Vinogradov, Maxim G.; Kurilov, Dmitry V.; Ferapontov, Vladimir A.; Heise, Glenn L.
Mendeleev Communications, 2003 , vol. 13, # 3 p. 125 - 126
反应条件
1: With sodium periodate in ethanol; water T=0°C; Oxidation; cleaved; 0.5 h; 2: With sodium tetrahydroborate in ethanol T=20°C; Reduction; 2 h;
参考文献
Katoch, Rita; Trivedi, Girish K.; Phadke, Ratna S.
Bioorganic and Medicinal Chemistry, 1999 , vol. 7, # 12 p. 2753 - 2758
反应条件
antimony(V) pentachloride; water in acetonitrile T=20°C; 0.166667 h;
参考文献
Gloria, Paulo M. C.; Prabhakar, Sundaresan; Lobo, Ana M.; Gomes, Mario J. S.
Tetrahedron Letters, 2003 , vol. 44, # 49 p. 8819 - 8821