(S)-(+)-1,2-异亚丙基甘油合成路线 （共 82 条）
反应条件
lithium borohydride in diethyl ether
参考文献
Bibak, Niloufar; Hajdu, Joseph
Tetrahedron Letters, 2003 , vol. 44, # 31 p. 5875 - 5877
反应条件
phosphate buffer; porcine pancreas T=28°C; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 7200
反应条件
lithium boron tetrafluoride in dichloromethane T=20°C; deprotection; 0.25 h;
参考文献
Chen, Anqi; Zheng, Yong; Zhou, Xinfeng
Synthetic Communications, 1999 , vol. 29, # 19 p. 3421 - 3423
反应条件
toluene-4-sulfonic acid in pentane 40 h; Heating;
参考文献
Ray, Peter C.; Roberts, Stanley M.
Tetrahedron Letters, 1999 , vol. 40, # 9 p. 1779 - 1782
反应条件
methanol in di-isopropyl ether T=0°C; 83 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Asymmetry, , vol. 8, # 6 p. 923 - 933
反应条件
lithium hydroxide hydrate in tetrahydrofuran; water T=20°C; 12 h;
参考文献
European Journal of Organic Chemistry, , # 20 p. 4311 - 4318
反应条件
lithium aluminium tetrahydride in tetrahydrofuran T=0°C;
参考文献
Tetrahedron Letters, , vol. 30, # 39 p. 5319 - 5322
反应条件
1: 1.) NaH / 1.) ether, 2.) -5 deg C, 15 min. 2: 85 percent / <PdCl2(PhCN)2> / tetrahydrofuran / 3 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 48, # 6 p. 1071 - 1080
反应条件
1: 1.) KH, 2.) K2CO3, MeOH / 1.) THF, 20 deg C, 3 h, 2.) 35 deg C, 1 h, H2O 2: 1.) NaH / 1.) ether, 2.) -5 deg C, 15 min. 3: 85 percent / <PdCl2(PhCN)2> / tetrahydrofuran / 3 h / 20 °C View Scheme
参考文献
Tetrahedron, , vol. 48, # 6 p. 1071 - 1080
反应条件
Pseudomonas fluorecens Amano AK lipase in ethyl acetate T=30°C; pH=7; 5 h; aq. phosphate bufferResolution of racemateEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Molecular Catalysis B: Enzymatic, , vol. 69, # 1-2 p. 42 - 46
