2,3,4-三甲氧基-6-甲基苯甲醛合成路线 （共 12 条）
反应条件
aluminium trichloride in dichloromethane T=25°C; 2 h;
参考文献
Bovicelli, Paolo; Borioni, Giorgio; Fabbrini, Danilo; Barontini, Maurizio
Synthetic Communications, 2008 , vol. 38, # 3 p. 391 - 400
反应条件
trichlorophosphate T=65°C; Vilsmeier-Haack reaction; 5 h;
参考文献
Ji, Yafei; Xu, Wanmei; Jin, Wenhu; Weimin, Yue
Synthetic Communications, 2006 , vol. 36, # 14 p. 1961 - 1965
反应条件
1: 97 percent / hydrazine hydrate; KOH / ethane-1,2-diol / 6 h / 70 - 120 °C 2: 95 percent / POCl3 / 5 h / 65 °C View Scheme
参考文献
Synthetic Communications, , vol. 36, # 14 p. 1961 - 1965
反应条件
trichlorophosphate T=40 - 80°C;
参考文献
Synthetic Communications, , vol. 34, # 22 p. 4049 - 4053
参考文献
Justus Liebigs Annalen der Chemie, , vol. 721, p. 220 - 222
反应条件
sodium hydrogen sulphate; dihydrogen peroxide in methanol Dakin reaction; 0.5 h;
参考文献
Bovicelli, Paolo; Borioni, Giorgio; Fabbrini, Danilo; Barontini, Maurizio
Synthetic Communications, 2008 , vol. 38, # 3 p. 391 - 400
反应条件
1: With dihydrogen peroxide; toluene-4-sulfonic acid in methanol T=30°C; 2.75 h; 2: With sodium dichromate in methanol; water T=20°C; 1.5 h;
参考文献
Lu, Liang; Chen, Fener
Synthetic Communications, 2004 , vol. 34, # 22 p. 4049 - 4053
反应条件
1: aq.H2SO4; aq.H2O2 / methanol / 10 - 20 °C 2: 17.6 g / benzene; polyglycol-400; aq.NaOH / H2O / 2.5 h / 55 °C / pH 9.0 - 9.5 View Scheme
参考文献
Ji, Yafei; Xu, Wanmei; Jin, Wenhu; Weimin, Yue
Synthetic Communications, 2006 , vol. 36, # 14 p. 1961 - 1965
反应条件
boron trichloride in dichloromethane T=-78°C; 2.5 h;
参考文献
Ishii; Ishikawa; Wada; Miyazaki; Kaneko; Harayama
Chemical and Pharmaceutical Bulletin, 1992 , vol. 40, # 10 p. 2614 - 2619
反应条件
1.1: p-TsOH; H2O2 / methanol / 2.75 h / 30 °C
1.2: Na2Cr2O7 / H2O; methanol / 1.5 h / 20 °C
2.1: acetic acid / 6 h / 20 °C
3.1: NaH / tetrahydrofuran / 0.5 h / 0 °C
3.2: tetrahydrofuran / 6.5 h / 0 °C
4.1: 17.2 g / 3 h / 85 °C / 7.5 Torr
View Scheme
参考文献
Lu, Liang; Chen, Fener
Synthetic Communications, 2004 , vol. 34, # 22 p. 4049 - 4053
