2-羟基-3,4-二甲氧基-6-甲基苯甲醛合成路线 （共 8 条）
反应条件
boron trichloride in dichloromethane T=-78°C; 2.5 h;
参考文献
Ishii; Ishikawa; Wada; Miyazaki; Kaneko; Harayama
Chemical and Pharmaceutical Bulletin, 1992 , vol. 40, # 10 p. 2614 - 2619
反应条件
1: 82.7 percent / POCl3 / 1 h / 90 °C 2: 78.3 percent / BCl3 / CH2Cl2 / 2.5 h / -78 °C View Scheme
参考文献
Aquila,H.
Justus Liebigs Annalen der Chemie, 1969 , vol. 721, p. 220 - 222
反应条件
1: N2H4*H2O, KOH, triethylene glycol 2: POCl3 3: AlCl3 View Scheme
参考文献
Aquila,H.
Justus Liebigs Annalen der Chemie, 1969 , vol. 721, p. 220 - 222
反应条件
potassium carbonate; acetone Behandeln des Reaktionsprodukts mit AlCl3 in Aether;
参考文献
Seshadri; Venkatasubramanian
Journal of the Chemical Society, 1959 , p. 1660
反应条件
in various solvent(s) T=210 - 215°C; 0.5 h;
参考文献
Ishii; Kaneko; Miyazaki; Harayama
Chemical and Pharmaceutical Bulletin, 1991 , vol. 39, # 11 p. 3100 - 3102
反应条件
in xylene 11 h; Heating;
参考文献
Harayama, Takashi; Katsuno, Keiko; Nishioka, Hiromi; Fujii, Masako; Nishita, Yoshitaka; et al.
Heterocycles, 1994 , vol. 39, # 2 p. 613 - 622
反应条件
1: K2S2O8; aq. NaOH solution
2: aqueous H2O2; aq. NaOH solution
View Scheme
参考文献
Seshadri; Venkatasubramanian
Journal of the Chemical Society, 1959 , p. 1660
反应条件
1: Zn-Hg, aq. HCl / toluene
2: (KO3S)2NO, aq. NaOAc
View Scheme
参考文献
Aquila,H.
Justus Liebigs Annalen der Chemie, 1969 , vol. 721, p. 220 - 222
