1-(甲硫基)-4-(三甲基硅烷基)-苯合成路线 (共 7 条)
反应条件
1: 1-bromo-4-methylsulfanyl benzene With iodine; magnesium; ethylene dibromide in diethyl ether 2: chloro-trimethyl-silane in diethyl ether Reflux;
参考文献
Lothian, Aileen P.; Ramsden, Christopher A.; Shaw, Maxine M.; Smith, Rachel G.
Tetrahedron, 2011 , vol. 67, # 15 p. 2788 - 2793
反应条件
potassium fluoride; water; 2-dicyclohexylphosphino-1,1'-biphenyl; tris-(dibenzylideneacetone)dipalladium(0) in 1,4-dioxane T=100°C; 24 h;
参考文献
McNeill, Eric; Barder, Timothy E.; Buchwald, Stephen L.
Organic Letters, 2007 , vol. 9, # 19 p. 3785 - 3788
反应条件
potassium carbonate; tris-(dibenzylideneacetone)dipalladium(0); bisphenyl-(pyridin-2-yl)phosphine in various solvent(s) T=100°C; Substitution; silylation;
参考文献
Goossen; Ferwanah
Synlett, 2000 , # 12 p. 1801 - 1803
反应条件
in diethyl ether Ambient temperature;
参考文献
Walree, Cornelis A. van; Lauteslager, Xavier Y.; Wageningen, Andreas M. A. van; Zwikker, Jan W.; Jenneskens, Leonardus W.
Journal of Organometallic Chemistry, 1995 , vol. 496, # 1 p. 117 - 126
反应条件
in tetrahydrofuran T=-30 - 20°C;
参考文献
Dunne, John P.; Tacke, Matthias; Selinka, Carola; Stalke, Dietmar
European Journal of Inorganic Chemistry, 2003 , # 7 p. 1416 - 1425
反应条件
XeF2 in hexafluorobenzene T=20°C; 1 h; Pyrex.(R). vessel;
参考文献
Lothian, Aileen P.; Ramsden, Christopher A.; Shaw, Maxine M.; Smith, Rachel G.
Tetrahedron, 2011 , vol. 67, # 15 p. 2788 - 2793
反应条件
methanol; perchloric acid T=50°C; Rate constant;
参考文献
Journal of the Chemical Society [Section] B: Physical Organic, , vol. <B>, p. 1446 - 1449