2-溴-1,1,1,3,3,4,4,5,5,5-十氟-2-三氟甲基戊烷合成路线 (共 18 条)
反应条件
bromine in benzonitrile 0.5 h; Ambient temperature;
参考文献
Smart, Bruce E.; Middleton, William J.; Farnham, William B.
Journal of the American Chemical Society, 1986 , vol. 108, # 16 p. 4905 - 4907
反应条件
bromine; cesium fluoride in acetonitrile T=40 - 50°C; 15 h;
参考文献
Postovoi, S. A.; Lantseva, L. T.; Zeifman, Yu. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 1 p. 199 - 202
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 1 p. 210 - 213
参考文献
Bayliff, Andrew E.; Bryce, Martin R.; Chambers, Richard D.; Matthews, Raymond S.
Journal of the Chemical Society, Chemical Communications, 1985 , # 15 p. 1018 - 1019
反应条件
lithium bromide in acetonitrile T=0°C; 0.25 h; also with LiI and LiCl, variation of time; Product distributionMechanism;
参考文献
Blume, Elisabeth; Gasafi-Martin, Waltraud; Probst, Anton; Werner, Konrad von
Journal of Fluorine Chemistry, 1991 , vol. 53, # 3 p. 387 - 396
反应条件
in ethyl acetate T=80°C; 12 h;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
in acetic acid T=110°C; 78 h;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
lithium iodide in acetonitrile T=0°C; 0.5 h; also with LiBr, variation of time and temperature; Product distributionMechanism;
参考文献
Blume, Elisabeth; Gasafi-Martin, Waltraud; Probst, Anton; Werner, Konrad von
Journal of Fluorine Chemistry, 1991 , vol. 53, # 3 p. 387 - 396
反应条件
tetrabutylammomium bromide in 1,2-dichloro-ethane T=20°C; var. nucleophiles and aolvents; Product distributionMechanism;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
tetrabutylammomium bromide in ethyl acetate T=20°C; 72 h; other alkenes, alkynes, and butadiene; var. solvents, nucleophiles, and temperature; Product distributionMechanism;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
tetrabutylammomium bromide in dichloromethane T=80°C; 7 h; other nucleophiles possible (NaN3, NaNO2, KSCN, KCN), other solvents possible (C2H4Cl2, ethyl acetate);
参考文献
Rozhkov, I. N.; Igumnov, S. M.; Pletnev, S. I.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 4.2 p. 856
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 4 p. 951