2-溴-1,1,1,3,3,4,4,5,5,5-十氟-2-三氟甲基戊烷合成路线 （共 18 条）
反应条件
tetrabutylammomium bromide in dichloromethane T=80°C; 7 h; other nucleophiles possible (NaN3, NaNO2, KSCN, KCN), other solvents possible (C2H4Cl2, ethyl acetate);
参考文献
Rozhkov, I. N.; Igumnov, S. M.; Pletnev, S. I.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 4.2 p. 856
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 4 p. 951
反应条件
tetrabutylammomium bromide in ethyl acetate T=20°C; 72 h; other alkenes, alkynes, and butadiene; var. solvents, nucleophiles, and temperature; Product distributionMechanism;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
lithium iodide in acetonitrile T=0°C; 0.5 h; also with LiBr, variation of time and temperature; Product distributionMechanism;
参考文献
Journal of Fluorine Chemistry, , vol. 53, # 3 p. 387 - 396
反应条件
tetrabutylammomium bromide in 1,2-dichloro-ethane T=20°C; var. nucleophiles and aolvents; Product distributionMechanism;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
tetrabutylammomium bromide; iodine in dichloromethane T=20°C; 50 h;
参考文献
Rozhkov, I. N.; Igumnov, S. M.; Pletnev, S. I.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 4.2 p. 856
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 4 p. 951
反应条件
in ethyl acetate T=80°C; 12 h;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
反应条件
tetrabutylammomium bromide in dichloromethane T=80°C; 7 h; other nucleophiles possible (NaN3, NaNO2, KSCN, KCN), other solvents possible (C2H4Cl2, ethyl acetate);
参考文献
Rozhkov, I. N.; Igumnov, S. M.; Pletnev, S. I.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1990 , vol. 39, # 4.2 p. 856
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1990 , # 4 p. 951
反应条件
tetrabutylammomium bromide in ethyl acetate T=20°C; 72 h; other alkenes, alkynes, and butadiene; var. solvents, nucleophiles, and temperature; Product distributionMechanism;
参考文献
Rozhkov, I. N.; Chaplina, I. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 12 p. 2451 - 2456
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , vol. 40, # 12 p. 2810 - 2815
