(3-甲基丁-2-烯基)丙二酸二乙酯合成路线 （共 59 条）
反应条件
1: sodium / ethanol
2: 40 g / ethanol / 1.) 15 deg C, 6 h, 2.) reflux, 0.5 h
View Scheme
参考文献
Cocker, Wesley; Geraghty, Niall W. A.; McMurry, T. Brian H.; Shannon, Patrick V. R.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 10 p. 2245 - 2254
反应条件
sodium hydride; NiCl2TBP in tetrahydrofuran
T=65°C; 36 h; further Ni catalysts; Product distribution;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
sodium hydride; NiCl2(dppb) in tetrahydrofuran
T=65°C; 36 h; further Ni catalysts; Product distribution;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
sodium hydride; NiCl2(dppb) in tetrahydrofuran
T=65°C; 36 h; Yield given. Yields of byproduct given;
参考文献
Alvarez, Eleuterio; Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1988 , vol. 339, p. 199 - 212
反应条件
methylmagnesium bromide; sodium hydride; NiCl2((PPh3)P)2 in tetrahydrofuran
T=65°C; 36 h; other reag.; other catalyst; other temp./react. time; other solvents; Product distribution;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1986 , vol. 317, p. 383 - 408
反应条件
sodium hydride; Bu4N[Fe(CO)3(NO)]
1.) THF, 10 min, 2.) THF, reflux, 12 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Xu, Yuanyao; Zhou, Bo
Journal of Organic Chemistry, 1987 , vol. 52, # 6 p. 974 - 977
反应条件
1: acetic acid; hydrogen bromide
2: alcohol
View Scheme
参考文献
Staudinger; Kreis; Schilt
Helvetica Chimica Acta, 1922 , vol. 5, p. 750
参考文献
Staudinger; Kreis; Schilt
Helvetica Chimica Acta, 1922 , vol. 5, p. 750
参考文献
Cuvigny,T.; Normant,H.
Bulletin de la Societe Chimique de France, 1961 , p. 2423 - 2433
反应条件
NiCl2TPP; isopropylmagnesium chloride in tetrahydrofuran
T=20°C; 36 h; var. ligands, temp., times; Product distribution;
参考文献
Cuvigny, Therese; Julia, Marc
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. C21 - C24
