1,1,2,2-四氯-1,3,3,3-四氟丙烷合成路线 （共 24 条）
反应条件
hydrogen fluoride; chlorine; chromium cobalt oxide in nitrogen T=300 - 400°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 22; 25 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 95/5 calcined at 900 C T=280 - 320°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (98percent chromium/2percent copper) treated with HF T=280°C; P=760.051 Torr; 0.00138889 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; copper-substituted α-chromium oxide (95percent chromium/5percent copper) treated with HF T=320°C; P=760.051 Torr; 0.00833333 h; Inert atmosphereMonel.(TM). nickel alloy tube packed with Monel.(TM). turnings; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Rosenfeld, H. David; Sievert, Allen; Subramoney, Shekhar
Patent: US2010/152503 A1, 2010 ;
Location in patent: Page/Page column 12 ;
反应条件
hydrogen fluoride; chlorine; cobalt(II) chromite in nitrogen T=375°C; P=760.051 Torr; 0.00416667 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2004/18397 A1, 2004 ;
Location in patent: Page 23; 25 ;
反应条件
water; chlorine T=35°C; Irradiation.mit UV-Licht;
参考文献
Fried; Miller
Journal of the American Chemical Society, 1959 , vol. 81, p. 2078,2081
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 98/2 calcined at 450 C T=320°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; chlorine; zinc alumina-supported catalyst T=280°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37743 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3/Zn(NO3)2 95/5 calcined at 450 C T=280°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37743 A1, 2005 ;
Location in patent: Page/Page column 15-16; 17 ;
反应条件
hydrogen fluoride; chlorine; Cr(NO3)3; AuCl3; NH4OH; calcined; Cr/Au=98/2 T=280 - 400°C; Product distribution / selectivity;
参考文献
Rao, Velliyur Nott Mallikarjuna; Sievert, Allen Capron; Rosenfeld, H. David; Subramoney, Shekhar
Patent: US2008/207964 A1, 2008 ;
Location in patent: Page/Page column 14-15 ;
