吲哚(2,3-B)环辛烯合成路线 （共 21 条）
反应条件
potassium phosphate; magnesium sulfate; acetic acid; Pd0(tris(tert-butyl)phosphine)2 in N,N-dimethyl acetamide T=140°C; 2 h;
参考文献
Nazare, Marc; Schneider, Claudia; Lindenschmidt, Andreas; Will, David William
Angewandte Chemie - International Edition, 2004 , vol. 43, # 34 p. 4526 - 4528
反应条件
1: With acetic acid; trifluoroacetic acid T=90°C; Fischer indole synthesis; 2 h; 2: With sodium hydrogencarbonate in water; ethyl acetate
参考文献
Talaz, Oktay; Saracoglu, Nurullah
Tetrahedron, 2010 , vol. 66, # 10 p. 1902 - 1910
反应条件
hydrogen; toluene-4-sulfonic acid; [rhodium(I)(carbonyl)2(acetylacetonate)] in 1,4-dioxane T=100°C; P=52504.2 Torr; 24 h;
参考文献
Organic and Biomolecular Chemistry, , vol. 4, # 2 p. 302 - 313
反应条件
1: c-octyl-Br With chloro-trimethyl-silane; magnesium; ethylene dibromide; lithium chloride; zinc dibromide in tetrahydrofuran T=25°C; 2 h; Inert atmosphere; 2: benzenediazonium tetrafluoroborate in tetrahydrofuran T=-60 - 25°C; Inert atmosphere; 3: in tetrahydrofuran T=125°C; 0.5 h; Inert atmosphereMicrowave irradiation;
参考文献
Haag, Benjamin A.; Zhang, Zhi-Guang; Li, Jin-Shan; Knochel, Paul
Angewandte Chemie - International Edition, 2010 , vol. 49, # 49 p. 9513 - 9516
反应条件
L-(+)-tartaric acid-urea melt T=70°C; Fischer Indole Synthesis; 1.5 h;
参考文献
Gore, Sangram; Baskaran, Sundarababu; Koenig, Burkhard
Organic Letters, 2012 , vol. 14, # 17 p. 4568 - 4571
反应条件
sulfuric acid in 1,4-dioxane 3 h; Heating;
参考文献
Linnepe, Petra; Schmidt, Axel M.; Eilbracht, Peter
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 2 p. 302 - 313
反应条件
sulfuric acid in acetic acid T=20°C; Fischer's indolization; 2 h;
参考文献
Tetrahedron, , vol. 56, # 49 p. 9641 - 9646
反应条件
dirhodium(II) tetraoctanoate in 1,2-dichloro-ethane T=70°C; 16 h; Inert atmosphereMolecular sieve;
参考文献
Sun, Ke; Liu, Sheng; Bec, Patryk M.; Driver, Tom G.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 7 p. 1702 - 1706
反应条件
1: CDCl3 2: 85 percent / 280 °C View Scheme
参考文献
Organic Letters, , vol. 5, # 11 p. 1999 - 2001
反应条件
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium hydroxide / 1,4-dioxane; water / 12 h / 80 °C / Inert atmosphere 2: trifluoromethanesulfonyl azide; copper(II) sulfate; triethylamine / methanol; dichloromethane; water / 20 °C / Inert atmosphere 3: dirhodium(II) tetraoctanoate / 1,2-dichloro-ethane / 16 h / 70 °C / Inert atmosphere; Molecular sieve View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 7 p. 1702 - 1706
