丁-1,3-二烯-2-基苯合成路线 （共 79 条）
反应条件
tungsten oxide-silver nitrate-niobium oxide silicon oxide-aluminium mixed catalyst
T=225°C;
参考文献
Nation. Agrol Co.
Patent: US2415878 , 1942 ;
反应条件
pyridine; hydroquinone
参考文献
Marvel; Woolford
Journal of Organic Chemistry, 1958 , vol. 23, p. 1658
反应条件
formaldehyd
T=400°C; 0.5 h; Further byproducts given;
参考文献
Tzeng, Dongjaw; Fong, Raymond H.; Soysa, H. S. Dilanjan; Weber, William P.
Journal of Organometallic Chemistry, 1981 , vol. 219, # 2 p. 153 - 161
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C / Inert atmosphere; Cooling with acetone-dry ice
1.2: -78 - 4 °C / Inert atmosphere
2.1: tris-(dibenzylideneacetone)dipalladium(0); [(R)-methoxy(furyl)BIPHEP]; cesium fluoride / tetrahydrofuran / 12 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Zhang, Ping; Le, Hai; Kyne, Robert E.; Morken, James P.
Journal of the American Chemical Society, 2011 , vol. 133, # 25 p. 9716 - 9719
反应条件
1: diisobutylaluminium hydride / dichloromethane / 0 °C / Inert atmosphere
2: tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide / dichloromethane; water / 20 °C / Inert atmosphere
3: tris-(dibenzylideneacetone)dipalladium(0); [(R)-methoxy(furyl)BIPHEP]; cesium fluoride / tetrahydrofuran; water / 36 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Zhang, Ping; Le, Hai; Kyne, Robert E.; Morken, James P.
Journal of the American Chemical Society, 2011 , vol. 133, # 25 p. 9716 - 9719
反应条件
1: tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide / dichloromethane; water / 20 °C / Inert atmosphere
2: tris-(dibenzylideneacetone)dipalladium(0); [(R)-methoxy(furyl)BIPHEP]; cesium fluoride / tetrahydrofuran; water / 36 h / 60 °C / Inert atmosphere
View Scheme
参考文献
Zhang, Ping; Le, Hai; Kyne, Robert E.; Morken, James P.
Journal of the American Chemical Society, 2011 , vol. 133, # 25 p. 9716 - 9719
参考文献
Tamao,K. et al.
Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 1958 - 1969
反应条件
potassium hydroxide; 18-crown-6 ether in hexane
1.) 35 deg C, 12 h, 2.) 70 deg C, 1 h;
参考文献
Caporusso, Anna Maria; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 5 p. 949 - 953
反应条件
sodium hydride
1) DMSO, room temperature, 15 min, 2) 130 deg C, 30 min; Yield given. Multistep reaction;
参考文献
Yurchenko; Kyrij; Likhotvorik; Melnik; Zaharzh; Bzhezovski; Kushko
Synthesis, 1991 , # 5 p. 393 - 394
反应条件
T=138.8 - 150.4°C; thermische Dissoziation; Kinetics;
参考文献
Backer; Bolt
Recueil des Travaux Chimiques des Pays-Bas, 1935 , vol. 54, p. 538,540
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Grummit; Leaver
Journal of the American Chemical Society, 1952 , vol. 74, p. 1595
