1-氨基-2,5-脱水-1-脱氧-D-甘露糖醇合成路线 （共 9 条）
反应条件
formic acid; hydrogen; palladium on activated charcoal in methanol T=20°C; Hydrogenolysis; P=760 Torr; 10 h;
参考文献
Claustre, Samantha; Bringaud, Frederic; Azema, Laurent; Baron, Rudi; Perie, Jacques; Willson, Michele
Carbohydrate Research, 1999 , vol. 315, # 3-4 p. 339 - 344
反应条件
hydrogen in methanol T=20°C; Hydrogenolysis; P=760 Torr; 16 h;
参考文献
Claustre, Samantha; Bringaud, Frederic; Azema, Laurent; Baron, Rudi; Perie, Jacques; Willson, Michele
Carbohydrate Research, 1999 , vol. 315, # 3-4 p. 339 - 344
反应条件
ammonia in methanol T=20°C; Hydrolysis; 0.5 h;
参考文献
Abdel-Rahman, Adel A.-H.; El Ashry, El Sayed H.; Schmidt, Richard R.
Carbohydrate Research, 1999 , vol. 315, # 1-2 p. 106 - 116
反应条件
hydrogen; nickel in ethanol T=25°C; Hydrogenation; 4 h;
参考文献
Carbohydrate Research, , vol. 317, # 1-4 p. 164 - 179
反应条件
1.1: sodium nitrite / H2O / 4 h / 0 °C 1.2: 87 percent / Dowex 1x8-50, CO3(2-) 2.1: 74 percent / NaBH3CN; HCl / methanol / 20 °C / pH 5.8 3.1: 71 percent / hydrogen / methanol / 16 h / 20 °C / 760 Torr View Scheme
参考文献
Carbohydrate Research, , vol. 315, # 3-4 p. 339 - 344
反应条件
1: 77 percent / hydroxylamine hydrochloride; sodium acetate / ethanol / 1.5 h 2: 60 percent / pyridine / 24 h / -5 °C 3: 90 percent / hydrogen / Pd(OH)2/C / dioxane; methanol / 4 h / 20 °C 4: 95 percent / ammonia / methanol / 0.5 h / 20 °C View Scheme
参考文献
Carbohydrate Research, , vol. 315, # 1-2 p. 106 - 116
反应条件
1: NaN3 / dimethylformamide / 24 h / 100 °C 2: H2 / Raney nickel / ethanol / 4 h / 25 °C View Scheme
参考文献
Carbohydrate Research, , vol. 317, # 1-4 p. 164 - 179
反应条件
1: pyridine / 18 h / -5 °C 2: NaN3 / dimethylformamide / 24 h / 100 °C 3: H2 / Raney nickel / ethanol / 4 h / 25 °C View Scheme
参考文献
Carbohydrate Research, , vol. 317, # 1-4 p. 164 - 179
反应条件
1: 90 percent / hydrogen / Pd(OH)2/C / dioxane; methanol / 4 h / 20 °C 2: 95 percent / ammonia / methanol / 0.5 h / 20 °C View Scheme
参考文献
Carbohydrate Research, , vol. 315, # 1-2 p. 106 - 116
