in water Kinetics; amt. of CO produced by decompn. of HCOONa at 240°C for 300 h was below of detection limit; const. rate estimated;

in water Kinetics; amt. of CO produced by decompn. of HCOONa at 240°C for 300 h was below of detection limit; const. rate estimated;

hydrogen in water-d2 Pd catalyst suspended in soln. of NaH(13)CO3 in D2O, H2 purged slowly; not isolated, detected by NMR;

hydrogen; mer-[RuH(NO)(tris(3-sulfonatophenyl)phosphine)3](9-) in water; water-d2 RuCl3(NO)(tris(3-sulfonatophenyl)phosphine)2(6-), tris(3-sulfonatophenyl)phosphine, NaH(13)CO3, TSPSA charged in medium pressure sapphire NMR tube under N2; filled with 30 bar CO2; 30 bar H2 added; shaken (70°C);

0.5 h; Heating;

sulfuric acid 7 h; Heating;