different temperatures and pressures; product yield; Rate constantMechanismKinetics;
参考文献
Haszeldine, Robert N.; Keen, David W.; Robinson, Peter J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 11 p. 1713 - 1718
toluene in neat (no solvent) pyrolysis in the presence of toluene;;
参考文献
Banks et al.
Journal of the Chemical Society, 1948 , p. 2190
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Emeleus; Haszeldine
Journal of the Chemical Society, 1949 , p. 2950
in tetrahydrofuran a suspn. of Rh complex in THF and CF3I in 1:2 molar ratio sealed in vacuo in a Pyrex reaction tube was either stirred or shaken for 4 h at 20°C; volatiles were removed under vac., trapped at -196°C and analyzed by GLC, residue was chromd. using hexane followed by benzene or CHCl3 as eluent, and recrystd. from a mixt. of either CHCl3 and EtOH or benzene and MeOH;
参考文献
Journal of Organometallic Chemistry, , vol. 224, # 2 p. 197 - 205