byproducts: OPF3; filling at -78°C, or chargeing total amt. of CF3COOAg in a layer between that of I2 and P; 195°C (120 h); further unidentified byproduct;
参考文献
Journal of the American Chemical Society, , vol. 79, p. 247
in dichloromethane adding Cd(CF3)2*DME and ClAuI2(PMe3) to an NMR tube (glove box), freezing CH2Cl2 into the reaction mixt., sealing at -80° under Ar, warming slowly to room temp., standing (6 h, room temp.); detected by 19F NMR;
in dichloromethane adding Cd(CF3)2*DME and CF3AuI2(PMe3) to an NMR tube (glove box), freezing CH2Cl2 into the reaction mixt., sealing at -80° under Ar, warming slowly to room temp., standing (6 h, room temp.); detected by 19F NMR;
in dichloromethane byproducts: CdI2; adding Cd(CF3)2*DME and I3Au(PPh3) to an NMR tube (glove box), freezing CH2Cl2 into the reaction mixt., sealing at -80° under Ar, warming slowly to room temp., standing (6 h, room temp.); detected by 19F NMR;
Gmelin Handbook: F: PerFHalOrg.3, 1.15, page 163 - 176
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Haszeldine, R. N.; West, B. O.
Journal of the Chemical Society, 1957 , p. 3880 - 3884
