112 h; Irradiationstatic and shaken tube, different reaction time (168 h); thermal conditions (200 deg C, 13 h); possible reaction pathways; Product distribution;
参考文献
Davies, Terry; Haszeldine, Robert N.; Tipping, Anthony E.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 927 - 932
in further solvent(s)
Irradiation (UV/VIS); heating a mixt. of 0.02 mole Me3SnCCPh and 0.17 mole CF3I to 90°C and UV irradn. in a sealed tube; removal of excess CF3I, distn. under reduced pressure;
参考文献
Klyuchinskii, S. A.; Zavgorodnii, V. S.; Lebedev, V. B.; Petrov, A. A.
Journal of General Chemistry USSR (English Translation), 1986 , vol. 56, p. 1474 - 1475
Zhurnal Obshchei Khimii, 1986 , vol. 56, p. 1663 - 1663
in neat (no solvent, gas phase)
Kinetics; react. in a flowing-afterglow reactor, carrier gas Ar (flow rate 0.05 mol/min, 1.5 Torr, 50°C); not isolated;
参考文献
Zhang, Fu Min; Oba, D.; Setser, D. W.
Journal of Physical Chemistry, 1987 , vol. 91, # 5 p. 1099 - 1114
Gmelin Handbook: F: PerFHalOrg.3, 1.9, page 70 - 123
Show Details
Bennet, F. W.; Emeleus, H. J.; Haszeldine, R. N.
Journal of the Chemical Society, 1953 , p. 1565 - 1571
