(E)-9-十四碳烯-1-醇乙酸酯合成路线 （共 31 条）
反应条件
1: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h
2: p-TsOH / methanol / 2 h / Heating
3: 90 percent / LiAlH4 / 1,2-dimethoxy-ethane / 48 h / 140 °C
4: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: p-TsOH / diethyl ether
2: 1.) 2M BuLi / 1.) hexane, HMPT, 0 deg C, 30 min, 2.)THF, r. t., 12 h
3: p-TsOH / methanol / 2 h / Heating
4: 90 percent / LiAlH4 / 1,2-dimethoxy-ethane / 48 h / 140 °C
5: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: 90 percent / LiAlH4 / 1,2-dimethoxy-ethane / 48 h / 140 °C
2: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: p-TsOH / methanol / 2 h / Heating
2: 90 percent / LiAlH4 / 1,2-dimethoxy-ethane / 48 h / 140 °C
3: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: 46.6 percent / Et3N / methanol / Ambient temperature; electrochemical reaction; Pt electrodes
2: 84.9 percent / LiAlH4 / diethyl ether
3: 86.6 percent / pyridine / benzene
View Scheme
参考文献
Singh, Krishna Nand; Singh, Manorama; Misra, Ram Achal
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1993 , vol. 32, # 4 p. 431 - 434
反应条件
1: 46.6 percent / Et3N / methanol / Ambient temperature; electrochemical reaction; Pt electrodes
2: 84.9 percent / LiAlH4 / diethyl ether
3: 86.6 percent / pyridine / benzene
View Scheme
参考文献
Singh, Krishna Nand; Singh, Manorama; Misra, Ram Achal
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1993 , vol. 32, # 4 p. 431 - 434
反应条件
1: 90 percent / acetonitrile / 24 h / Heating
2: NaOEt / tetrahydrofuran / 1 h / 25 °C
3: n-BuLi / toluene / 2 h / 25 °C
4: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
5: pyridine / 24 h / 25 °C
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: n-BuLi / toluene / 2 h / 25 °C
2: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
3: pyridine / 24 h / 25 °C
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: lead tetraacetate
2: n-BuLi / toluene / 2 h / 25 °C
3: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
4: pyridine / 24 h / 25 °C
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: n-BuLi / toluene / 2 h / 25 °C
2: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
3: pyridine / 24 h / 25 °C
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
