1-(3-甲氧基苯基)乙醇合成路线 （共 28 条）
反应条件
solid phase supported Candida antarctica lipase type B in tert-butyl methyl ether T=30°C; 4 h; Inert atmosphereEnzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 74, # 15 p. 5304 - 5310
反应条件
N-ethyl-N,N-diisopropylamine; CF3-PIP in chloroform T=0°C; 8 - 8.25 h; Resolution of racemate; Product distribution / selectivity;
参考文献
US2005/256150 A1, ;
Page/Page column 15; 16; 18 ;
反应条件
lyophilized cells of Rhodococcus ruber DSM 44541; acetone in phosphate buffer T=24°C; pH=8.0; 24 h; Title compound not separated from byproducts.;
参考文献
Journal of Organic Chemistry, , vol. 68, # 2 p. 402 - 406
反应条件
(R)-5-CF3-2-Ph-2,3-dihydroimidazo[1,2-a]pyridine; N-ethyl-N,N-diisopropylamine in chloroform 8 h; cooling; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 126, # 39 p. 12226 - 12227
反应条件
(1S,2R)-(+)-erythro-2-amino-1,2-diphenylethanol; benzoic acid in water; acetonitrile T=20°C;
参考文献
Chemistry - A European Journal, , vol. 13, # 7 p. 2144 - 2152
反应条件
1: 75 percent / 1.) aq. NaNO2, aq. HCl, 2.) KI / 1.) 0 deg C, 20 min, 2.) room temperature, 5 h 2: 89 percent / (-)-B-chlorodiisopinocampheylborane / tetrahydrofuran / 19 h / -25 °C 3: LiAlH4 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 63, # 22 p. 7674 - 7679
反应条件
1: 89 percent / (-)-B-chlorodiisopinocampheylborane / tetrahydrofuran / 19 h / -25 °C 2: LiAlH4 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 63, # 22 p. 7674 - 7679
反应条件
bis(norbornadiene)rhodium(I) tetrafluoroborate; C67H63N2O7P; C67H63N2O7P; diethylzinc; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in tetrahydrofuran T=0 - 20°C; Inert atmosphere; optical yield given as percent ee;
参考文献
Chemical Communications, , vol. 48, # 2 p. 263 - 265
反应条件
1: With 4-bromooctafluorobutanetriethoxysilane; H2O*Rh(2+)*2C2H3O2(1-)*C18H24N2O2 in toluene T=30°C; 1 h; 2: With potassium fluoride; dihydrogen peroxide; potassium hydrogencarbonate in tetrahydrofuran; methanol enantioselective reaction;
参考文献
Synlett, , vol. 23, # 20 p. 2957 - 2960
反应条件
C32H31Cl2N4OPRu; potassium isopropoxide T=30°C; P=750.075 Torr; 0.166667 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 18, # 35 p. 10843 - 10846
