1-苯基-1,2-环氧丙烷合成路线 (共 29 条)
反应条件
alkaline hydrogen peroxide; lithium triethylborohydride in tetrahydrofuran T=0°C; 1 h; var. time, var. reducing agent, isotope effect; Rate constantProduct distributionMechanism;
参考文献
Fort, Yves; Vanderesse, Regis; Caubere, Paul
Tetrahedron Letters, 1985 , vol. 26, # 26 p. 3111 - 3114
反应条件
in toluene N2 atmosphere, 80°C, 20 h; olefine: GC; pptd. complex: elem. anal.;
参考文献
Moloy, Kenneth G.
Inorganic Chemistry, 1988 , vol. 27, p. 677 - 681
反应条件
water; diethylamine 1.) benzene, 10 h; 2.) ether; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Akita, M.; Matsuoka, K.; Asami, K.; Yasuda, H.; Nakamura, A.
Journal of Organometallic Chemistry, 1987 , vol. 327, p. 193 - 210
反应条件
sodium tert-pentoxide; sodium hydride; zinc(II) chloride in ethylene glycol dimethyl ether T=65°C; 6 h;
参考文献
Fort, Yves; Vanderesse, Regis; Caubere, Paul
Tetrahedron Letters, 1985 , vol. 26, # 26 p. 3111 - 3114
反应条件
alkaline hydrogen peroxide; lithium triethylborohydride in tetrahydrofuran T=0°C; 1 h; var. time, var. reducing agent, isotope effect; Rate constantProduct distributionMechanism;
参考文献
Fort, Yves; Vanderesse, Regis; Caubere, Paul
Tetrahedron Letters, 1985 , vol. 26, # 26 p. 3111 - 3114
反应条件
(tetraphenylporphinato)Fe(ClO4) in 1,4-dioxane T=80°C; 2.5 h;
参考文献
Chemistry Letters, , # 12 p. 1031 - 1032
反应条件
C12H6F18Fe3O16 in 1,2-dichloro-ethane T=80°C; 1 h; Inert atmosphere; regioselective reaction;
参考文献
Tetrahedron, , vol. 66, # 13 p. 2373 - 2377
反应条件
silicon tetrafluoride; N-ethyl-N,N-diisopropylamine in 1,2-dichloro-ethane
参考文献
Tetrahedron Letters, , vol. 29, # 33 p. 4101 - 4104
反应条件
hydrogen bromide; phenol 1.) 100 deg C, 24 h; Yield given. Multistep reaction;
参考文献
Christol, Henri; Grelet, Danielle; Darvich, Mohammad Raouf; Fallouh, Fayez; Plenat, Francoise; Cristau, Henri-Jean
Bulletin de la Societe Chimique de France, 1989 , # 4 p. 477 - 483
反应条件
C68H92Cr2N8O4(2+)*2Cl(1-) in methanol; dichloromethane T=20°C; 18 h; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron, , vol. 67, # 43 p. 8300 - 8307