9-苯基-9-硼杂双环[3.3.1]壬烷合成路线 （共 28 条）
反应条件
in tetrahydrofuran; diethyl ether T=20°C; 3 h;
参考文献
Fang, Guang Y.; Wallner, Olov A.; Di Blasio, Nadia; Ginesta, Xavier; Harvey, Jeremy N.; Aggarwal, Varinder K.
Journal of the American Chemical Society, 2007 , vol. 129, # 47 p. 14632 - 14639
反应条件
1: in tetrahydrofuran T=0°C; Alkylation; Grignard-reaction; 0.75 h; 2: T=100°C; Decomposition; P=0.5 Torr;
参考文献
Soderquist, John A.; Justo De Pomar, Jorge C.
Tetrahedron Letters, 2000 , vol. 41, # 19 p. 3537 - 3539
反应条件
in various solvents T=20°C; 12 h;
参考文献
Kimura, Masanari; Mori, Masahiko; Tamaru, Yoshinao
Chemical Communications, 2007 , # 43 p. 4504 - 4506
反应条件
in tetrahydrofuran; diethyl ether byproducts: H2; Ar-atmosphere; dropwise addn. of PhLi in Et2O to 9-BBN in THF (0°C), dropwise addn. of CH3SO3H; distn.;
参考文献
Kalbarczyk, E.; Pasynkiewicz, S.
Journal of Organometallic Chemistry, 1985 , vol. 292, p. 119 - 132
反应条件
in tetrahydrofuran; diethyl ether byproducts: Cu, Li, C6H6; to the soln. of copper(I) iodide/ether/THF phenyl-lithium was added at 0°C, stirred for 10 min, cooled to -78°C, 9-BBN was added,allowed to warm to room temp, stirred for 1 h; decanted off, evapd. in vac., distd.;
参考文献
Whiteley, Chris G.
Journal of the Chemical Society, Chemical Communications, 1981 , # 1 p. 5 - 6
反应条件
(i), (ii) MeSO3H; Multistep reaction;
参考文献
Crombie, Aimee L.; Kane Jr., John L.; Shea, Kevin M.; Danheiser, Rick L.
Journal of Organic Chemistry, 2004 , vol. 69, # 25 p. 8652 - 8667
反应条件
1.1: 85 percent / 12 h / 135 - 150 °C 2.1: tetrahydrofuran / 0.75 h / 0 °C 2.2: 90 percent / 100 °C / 0.5 Torr View Scheme
参考文献
Soderquist, John A.; Justo De Pomar, Jorge C.
Tetrahedron Letters, 2000 , vol. 41, # 19 p. 3537 - 3539
反应条件
in diethyl ether Inert atmosphere;
参考文献
Zultanski, Susan L.; Fu, Gregory C.
Journal of the American Chemical Society, 2011 , vol. 133, # 39 p. 15362 - 15364
反应条件
Multistep reaction. Title compound not separated from byproducts.;
参考文献
Stymiest, Jake L.; Dutheuil, Guillaume; Mahmood, Adeem; Aggarwal, Varinder K.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 39 p. 7491 - 7494
反应条件
triphenyl phosphite; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in 1,4-dioxane T=80°C; Suzuki-Miyaura coupling; 6 h;
参考文献
Kayaki, Yoshihito; Koda, Takashi; Ikariya, Takao
European Journal of Organic Chemistry, 2004 , # 24 p. 4989 - 4993
