9-苯基-9-硼杂双环[3.3.1]壬烷合成路线 （共 28 条）
反应条件
Multistep reaction. Title compound not separated from byproducts.;
参考文献
Stymiest, Jake L.; Dutheuil, Guillaume; Mahmood, Adeem; Aggarwal, Varinder K.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 39 p. 7491 - 7494
反应条件
1,1-dimethylpropan-1-ol; ((Me)N2N)Ni-Cl; sodium iodide; sodium hydroxide in 1,4-dioxane
T=80°C; Suzuki-Miyaura Coupling; 24 h; Inert atmosphere;
参考文献
Di Franco, Thomas; Boutin, Nicolas; Hu, Xile
Synthesis (Germany), 2013 , vol. 45, # 21 art. no. SS-2013-Z0609-FA, p. 2949 - 2958
反应条件
1: phenyl-(9-BBN) With lithium tert-butylate in 2-methyl-propan-1-ol; benzene
T=20°C; 0.333333 h; Schlenk techniqueInert atmosphere;
2: 1-bromo-1-methylcyclohexane With [(diglyme)NiBr2]; 4,4'-di-tert-butyl-2,2'-dipyridyl in 2-methyl-propan-1-ol; benzene
T=20 - 40°C; Suzuki Coupling; 28.5 h; Schlenk techniqueInert atmosphere; ConcentrationReagent/catalystSolvent;
参考文献
Zultanski, Susan L.; Fu, Gregory C.
Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 624 - 627
反应条件
1: phenyl-(9-BBN) With lithium tert-butylate in 2-methyl-propan-1-ol; toluene
T=20°C; 0.333333 h; Schlenk techniqueInert atmosphere;
2: 1-bromo-1-methylcyclohexane With [(diglyme)NiBr2]; 4,4'-di-tert-butyl-2,2'-dipyridyl in 2-methyl-propan-1-ol; toluene
T=20 - 40°C; Suzuki Coupling; 28.5 h; Schlenk techniqueInert atmosphere;
参考文献
Zultanski, Susan L.; Fu, Gregory C.
Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 624 - 627
反应条件
1,1-dimethylpropan-1-ol; ((Me)N2N)Ni-Cl; sodium iodide; sodium hydroxide in 1,4-dioxane
T=80°C; Suzuki-Miyaura Coupling; 24 h; Inert atmosphere;
参考文献
Di Franco, Thomas; Boutin, Nicolas; Hu, Xile
Synthesis (Germany), 2013 , vol. 45, # 21 art. no. SS-2013-Z0609-FA, p. 2949 - 2958
反应条件
1,1-dimethylpropan-1-ol; ((Me)N2N)Ni-Cl; sodium iodide; sodium hydroxide in 1,4-dioxane
T=80°C; Suzuki-Miyaura Coupling; 24 h; Inert atmosphere;
参考文献
Di Franco, Thomas; Boutin, Nicolas; Hu, Xile
Synthesis (Germany), 2013 , vol. 45, # 21 art. no. SS-2013-Z0609-FA, p. 2949 - 2958
反应条件
1,1-dimethylpropan-1-ol; ((Me)N2N)Ni-Cl; sodium iodide; sodium hydroxide in 1,4-dioxane
T=80°C; Suzuki-Miyaura Coupling; 24 h; Inert atmosphere;
参考文献
Di Franco, Thomas; Boutin, Nicolas; Hu, Xile
Synthesis (Germany), 2013 , vol. 45, # 21 art. no. SS-2013-Z0609-FA, p. 2949 - 2958
反应条件
1: phenyl-(9-BBN) With lithium tert-butylate in 2-methyl-propan-1-ol; benzene
T=20°C; 0.333333 h; Schlenk techniqueInert atmosphere;
2: triethylcarbinyl bromide With [(diglyme)NiBr2]; 4,4'-di-tert-butyl-2,2'-dipyridyl in 2-methyl-propan-1-ol; benzene
T=20 - 40°C; Suzuki Coupling; 28.5 h; Schlenk techniqueInert atmosphere;
参考文献
Zultanski, Susan L.; Fu, Gregory C.
Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 624 - 627
