反应条件
1: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With C16H26N(1+)*BF4(1-); copper(l) chloride; sodium t-butanolate in tetrahydrofuran
T=20°C; 0.5 h; Schlenk techniqueInert atmosphere;
2: 4-(but-2-yn-1-yloxy)-4-methylcyclohexa-2,5-dienone With methanol in tetrahydrofuran
T=20°C; 48 h; Schlenk techniqueInert atmosphere; enantioselective reaction;
参考文献
Liu, Ping; Fukui, Yuki; Tian, Ping; He, Zhi-Tao; Sun, Cai-Yun; Wu, Nuo-Yi; Lin, Guo-Qiang
Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 11700 - 11703
